Crystal engineering based on polymeric hydrogen-bonded supramolecules by self-assembling of 4,4 '-(9-fluorenylidene)diphenol and 4,4 '-cyclohexylidenebisphenol with bipyridines | |
Zeng, QD; Wu, DX; Liu, CM; Ma, HW; Lu, J; Xu, SD; Li, Y; Wang, C; Bai, CL | |
刊名 | CRYSTAL GROWTH & DESIGN
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2005-05-01 | |
卷号 | 5期号:3页码:1041-1047 |
ISSN号 | 1528-7483 |
DOI | 10.1021/cg049650v |
英文摘要 | 4,4'-(9-Fluorenylidene)diphenol (FDP) and/or 4,4'-cyclohexylidenebisphenol (CBP) is crystallized with bipyridine bases 4,4'-bipyridyl (bipy), 1,2-bis(4-pyridyl)ethane (bipy-eta), 1,2-di(4-pyridyl)ethylene (dipy-ete), and 4,4'-dipyridyl N,N'-dioxide (dipy-dox) to afford molecular complexes (FDP)-(bipy) 1, (FDP)-(bipy-eta)(0.5) 2, (FDP)(2)- (dipy-ete) 3, (FDP)-(dipy-dox) 4, and (CBP)-(bipy) 5. The crystal structures of 1-5 have been determined by single-crystal X-ray diffraction. All these molecular complexes exhibit polymeric supramolecular structures via O-H---N or O-H---O hydrogen-bonding. I forms double helices. 2 forms an infinite honeycomblike supramolecular structure. 3 forms a brick supramolecular structure. 4 forms an X-shaped supramolecular structure. 5 forms a single strand infinite helix. Thus, by changing the guest molecule, we can obtain different supramolecular hydrogen-bonded polymers through interactions of host-guest systems. |
语种 | 英语 |
出版者 | AMER CHEMICAL SOC |
WOS记录号 | WOS:000228940600028 |
内容类型 | 期刊论文 |
源URL | [http://ir.iccas.ac.cn/handle/121111/56695] ![]() |
专题 | 中国科学院化学研究所 |
通讯作者 | Zeng, QD |
作者单位 | Chinese Acad Sci, Inst Chem, Ctr Mol Sci, Beijing 100080, Peoples R China |
推荐引用方式 GB/T 7714 | Zeng, QD,Wu, DX,Liu, CM,et al. Crystal engineering based on polymeric hydrogen-bonded supramolecules by self-assembling of 4,4 '-(9-fluorenylidene)diphenol and 4,4 '-cyclohexylidenebisphenol with bipyridines[J]. CRYSTAL GROWTH & DESIGN,2005,5(3):1041-1047. |
APA | Zeng, QD.,Wu, DX.,Liu, CM.,Ma, HW.,Lu, J.,...&Bai, CL.(2005).Crystal engineering based on polymeric hydrogen-bonded supramolecules by self-assembling of 4,4 '-(9-fluorenylidene)diphenol and 4,4 '-cyclohexylidenebisphenol with bipyridines.CRYSTAL GROWTH & DESIGN,5(3),1041-1047. |
MLA | Zeng, QD,et al."Crystal engineering based on polymeric hydrogen-bonded supramolecules by self-assembling of 4,4 '-(9-fluorenylidene)diphenol and 4,4 '-cyclohexylidenebisphenol with bipyridines".CRYSTAL GROWTH & DESIGN 5.3(2005):1041-1047. |
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