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Synthesis of mesoporous SrCO3 spheres and hollow CaCO3 spheres in room-temperature ionic liquid
Du, JM; Liu, ZM; Li, ZH; Han, BX; Huang, Y; Zhang, JL
刊名MICROPOROUS AND MESOPOROUS MATERIALS
2005-09-01
卷号83期号:1-3页码:145-149
关键词Srco3 Caco3 Ionic Liquid Xrd Refluxing
ISSN号1387-1811
DOI10.1016/j.micromeso.2005.04.005
英文摘要Mesoporous SrCO3 spheres with diameter ranging from 200 to 400 nm were synthesized via refluxing the solution of SrCl2 (.) 6H(2)O and sodium hydroxide in 1,1,3,3-tetramethylguanidinium lactate at 140 degrees C in the presence Of CO2. The morphology and structure of the as-prepared products were characterized by X-ray diffraction, scanning electron microscopy, and transmission electron microscopy. Nitrogen sorption measurements revealed that the obtained products exhibited high BET surface area of 69.4 m(2) g(-1) and average pore size of 5.7 nm with narrow pore size distribution. For comparison, CaCl2 was used to synthesize CaCO3 at the same experimental conditions, resulting in hollow calcite spheres and peanut-like structure calcite whose shell thickness and core diameter were about 100 nm and 200 nm, respectively. The BET surface area of the hollow calcite spheres calculated from N-2 adsorption is 17.03 m(2) g(-1). (c) 2005 Elsevier Inc. All rights reserved.
语种英语
出版者ELSEVIER SCIENCE BV
WOS记录号WOS:000231796600017
内容类型期刊论文
源URL[http://ir.iccas.ac.cn/handle/121111/56171]  
专题中国科学院化学研究所
通讯作者Liu, ZM
作者单位Chinese Acad Sci, Ctr Mol Sci, CAS Key Lab Colloid Interfacial & Chem Thermodyna, Inst Chem, Beijing 100080, Peoples R China
推荐引用方式
GB/T 7714
Du, JM,Liu, ZM,Li, ZH,et al. Synthesis of mesoporous SrCO3 spheres and hollow CaCO3 spheres in room-temperature ionic liquid[J]. MICROPOROUS AND MESOPOROUS MATERIALS,2005,83(1-3):145-149.
APA Du, JM,Liu, ZM,Li, ZH,Han, BX,Huang, Y,&Zhang, JL.(2005).Synthesis of mesoporous SrCO3 spheres and hollow CaCO3 spheres in room-temperature ionic liquid.MICROPOROUS AND MESOPOROUS MATERIALS,83(1-3),145-149.
MLA Du, JM,et al."Synthesis of mesoporous SrCO3 spheres and hollow CaCO3 spheres in room-temperature ionic liquid".MICROPOROUS AND MESOPOROUS MATERIALS 83.1-3(2005):145-149.
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