Ionic liquid solvent based on cyclic guanidinium cation for nucleophilic displacement reactions | |
Lin, YJ; Qiu, ZM; Duan, HF; Li, SH; Zhang, SB | |
刊名 | CHEMICAL RESEARCH IN CHINESE UNIVERSITIES |
2004 | |
卷号 | 20期号:1页码:46-49 |
关键词 | Ionic Liquid Cyclic Guanidinium Nucleophilicity |
ISSN号 | 1005-9040 |
英文摘要 | The nucleophilic displacement reaction of n-bromooctane and potassium iodide in ionic liquid based on cyclic guanidinium cation(2) was investigated. The kinetic reasult shows that the rate of the reaction is enhanced in ionic liquid (2). The same reaction in [bmim][PF6](1)(where bmim = 1-butyl-3-methylimidazolium) was also studied. It was found that as a reaction medium ionic liquid (2) is better than (1) for nucelophilic displacement reactions. |
语种 | 英语 |
出版者 | HIGHER EDUCATION PRESS |
WOS记录号 | WOS:000188933700012 |
内容类型 | 期刊论文 |
源URL | [http://ir.iccas.ac.cn/handle/121111/55347] |
专题 | 中国科学院化学研究所 |
通讯作者 | Zhang, SB |
作者单位 | 1.Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China 2.Jilin Univ, Coll Chem, Changchun 130023, Peoples R China |
推荐引用方式 GB/T 7714 | Lin, YJ,Qiu, ZM,Duan, HF,et al. Ionic liquid solvent based on cyclic guanidinium cation for nucleophilic displacement reactions[J]. CHEMICAL RESEARCH IN CHINESE UNIVERSITIES,2004,20(1):46-49. |
APA | Lin, YJ,Qiu, ZM,Duan, HF,Li, SH,&Zhang, SB.(2004).Ionic liquid solvent based on cyclic guanidinium cation for nucleophilic displacement reactions.CHEMICAL RESEARCH IN CHINESE UNIVERSITIES,20(1),46-49. |
MLA | Lin, YJ,et al."Ionic liquid solvent based on cyclic guanidinium cation for nucleophilic displacement reactions".CHEMICAL RESEARCH IN CHINESE UNIVERSITIES 20.1(2004):46-49. |
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