Asymmetric hydration of alkenes catalyzed by wool-palladium complex

doi:10.1002/pat.440

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	Asymmetric hydration of alkenes catalyzed by wool-palladium complex
	Xue, L; Jia, B; Tang, L; Ji, XF; Huang, MY; Jiang, YY
刊名	POLYMERS FOR ADVANCED TECHNOLOGIES
	2004-06-01
卷号	15 期号:6 页码:346-349
关键词	Wool-pd Complex Asymmetric Hydration 1-octene 1-decene (r)-(+)-2-octanol (s)-(+)-2-decanol
ISSN号	1042-7147
DOI	10.1002/pat.440
英文摘要	A wool-palladium complex has been found to be able to catalyze the asymmetric hydration of 1-octene to (S)-(+)-2-octanol and 1-decene to (R)-(+)-2-decanol under 1 atm N-2 and at 70degreesC. The optical yields were greatly affected by Pd content in wool-palladium complex, reaction time and so on, when the proper conditions were selected, (S)-(+)-2-octanol and (R)-(+)-2-decanol could be obtained in 83.2 and 75.6%e.e. optical yield respectively. This chiral natural biopolymer-palladium complex catalyst was very easy to prepare and could be reused several times without appreciable change in catalytic activity. Copyright (C) 2004 John Wiley Sons, Ltd.
语种	英语
出版者	JOHN WILEY & SONS LTD
WOS记录号	WOS:000221802200010
内容类型	期刊论文
源URL	[http://ir.iccas.ac.cn/handle/121111/55215]
专题	中国科学院化学研究所
通讯作者	Jia, B
作者单位	Chinese Acad Sci, Inst Chem, Grp 4060, Beijing 100080, Peoples R China
推荐引用方式 GB/T 7714	Xue, L,Jia, B,Tang, L,et al. Asymmetric hydration of alkenes catalyzed by wool-palladium complex[J]. POLYMERS FOR ADVANCED TECHNOLOGIES,2004,15(6):346-349.
APA	Xue, L,Jia, B,Tang, L,Ji, XF,Huang, MY,&Jiang, YY.(2004).Asymmetric hydration of alkenes catalyzed by wool-palladium complex.POLYMERS FOR ADVANCED TECHNOLOGIES,15(6),346-349.
MLA	Xue, L,et al."Asymmetric hydration of alkenes catalyzed by wool-palladium complex".POLYMERS FOR ADVANCED TECHNOLOGIES 15.6(2004):346-349.