Novel Polyethylenes via Late Transition Metal Complex Pre-catalysts

doi:10.1007/12_2013_212

CORC > 化学研究所 > 中国科学院化学研究所

	Novel Polyethylenes via Late Transition Metal Complex Pre-catalysts
	Sun, Wen-Hua; Kaminsky, W
刊名	POLYOLEFINS: 50 YEARS AFTER ZIEGLER AND NATTA II: POLYOLEFINS BY METALLOCENES AND OTHER SINGLE-SITE CATALYSTS
	2013
卷号	258 页码:163-178
关键词	Branched Polyethylene Ethylene Oligomerization Late-transition Metal Linear Polyethylene Polymerization
ISSN号	0065-3195
DOI	10.1007/12_2013_212
英文摘要	Late-transition metal complex pre-catalysts provide alternative promising catalytic systems for ethylene oligomerization and/or polymerization. Ethylene oligomerization using either iron or cobalt complex pre-catalysts is recognized as one of most active catalytic systems with high selectivity for a-olefins (up to 99%). New characteristic features are observed for the polyethylenes obtained from such late-transition metal catalytic systems. Highly linear polyethylene is usually obtained using the iron or cobalt complex pre-catalysts, whereas highly branched polyethylene is commonly formed by the nickel or palladium complex pre-catalysts. The causes for production of linear or branched polyethylenes are briefly explained according to the polymerization mechanism. Driven by demanding for new promising catalytic processes, the discussion is divided on the basis of models of complex pre-catalysts: a section on iron and cobalt complexes and another section on nickel and palladium complexes. The iron and nickel complex pre-catalysts receive more attention due to the relatively cheap and low toxicity metals from which they are derived.
语种	英语
出版者	SPRINGER-VERLAG BERLIN
WOS记录号	WOS:000335560000007
内容类型	期刊论文
源URL	[http://ir.iccas.ac.cn/handle/121111/54843]
专题	中国科学院化学研究所
通讯作者	Sun, Wen-Hua
作者单位	Chinese Acad Sci, Inst Chem, Beijing 100190, Peoples R China
推荐引用方式 GB/T 7714	Sun, Wen-Hua,Kaminsky, W. Novel Polyethylenes via Late Transition Metal Complex Pre-catalysts[J]. POLYOLEFINS: 50 YEARS AFTER ZIEGLER AND NATTA II: POLYOLEFINS BY METALLOCENES AND OTHER SINGLE-SITE CATALYSTS,2013,258:163-178.
APA	Sun, Wen-Hua,&Kaminsky, W.(2013).Novel Polyethylenes via Late Transition Metal Complex Pre-catalysts.POLYOLEFINS: 50 YEARS AFTER ZIEGLER AND NATTA II: POLYOLEFINS BY METALLOCENES AND OTHER SINGLE-SITE CATALYSTS,258,163-178.
MLA	Sun, Wen-Hua,et al."Novel Polyethylenes via Late Transition Metal Complex Pre-catalysts".POLYOLEFINS: 50 YEARS AFTER ZIEGLER AND NATTA II: POLYOLEFINS BY METALLOCENES AND OTHER SINGLE-SITE CATALYSTS 258(2013):163-178.