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Photochromism of diarylethenes containing dithieno[3,2-b:2 ',3 '-d]thiophene
Wang, Hongke1,2; Xu, Wei1; Zhu, Daoben1
刊名DYES AND PIGMENTS
2013-05-01
卷号97期号:2页码:303-310
关键词Photochromism Diarylethene Diarylethene Dimer Electrochemistry Single Crystal Intramolecular Excited Energy Transfer
ISSN号0143-7208
DOI10.1016/j.dyepig.2013.01.011
英文摘要Novel photochromic diarylethene and diarylethene dimer containing dithieno[3,2-b:2',3'-d]thiophene were designed and synthesized to compare their photochromic properties. Photochromism in solution and in the crystalline phase, fluorescence, electrochemical character, and theoretical calculations of the two compounds were studied. Both of them showed remarkable photochromic performance in the solution as well as in the crystalline phase. In the photostationary state, the conversion ratio in solution and in the crystalline phase from open-ring isomer to closed-ring isomer under irradiation was estimated by HPLC analysis. However, for diarylethene dimer, it showed higher fluorescent modulation efficiency while its photocyclization could only take place at one of the two diarylethene units due to the intramolecular excited energy transfer. (C) 2013 Elsevier Ltd. All rights reserved.
语种英语
出版者ELSEVIER SCI LTD
WOS记录号WOS:000316437700006
内容类型期刊论文
源URL[http://ir.iccas.ac.cn/handle/121111/53969]  
专题中国科学院化学研究所
通讯作者Xu, Wei
作者单位1.Chinese Acad Sci, Inst Chem, Organ Solid Lab, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China
2.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China
推荐引用方式
GB/T 7714
Wang, Hongke,Xu, Wei,Zhu, Daoben. Photochromism of diarylethenes containing dithieno[3,2-b:2 ',3 '-d]thiophene[J]. DYES AND PIGMENTS,2013,97(2):303-310.
APA Wang, Hongke,Xu, Wei,&Zhu, Daoben.(2013).Photochromism of diarylethenes containing dithieno[3,2-b:2 ',3 '-d]thiophene.DYES AND PIGMENTS,97(2),303-310.
MLA Wang, Hongke,et al."Photochromism of diarylethenes containing dithieno[3,2-b:2 ',3 '-d]thiophene".DYES AND PIGMENTS 97.2(2013):303-310.
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