All-polymer solar cells based on PTACs/P3HT blends with large open-circuit voltage | |
Kang, Hongwei1,2; Zheng, Yu-Qing3; Jiang, Wei1; Xiao, Chengyi1,2; Wang, Jie-Yu3; Pei, Jian3; Wang, Zhaohui1 | |
刊名 | DYES AND PIGMENTS
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2013-12-01 | |
卷号 | 99期号:3页码:1065-1071 |
关键词 | Perylene Esters D-a Conjugated Polymers Electron Acceptor Blending Large Open-circuit Voltage All-polymer Solar Cells |
ISSN号 | 0143-7208 |
DOI | 10.1016/j.dyepig.2013.08.017 |
英文摘要 | Four D-A polymers alternated between 3,4,9,10-tetra(n-alkoxy-carbonyl)-perylenes (PTACs) and thiophene derivatives (TT and BDT) in backbones were synthesized under Stille coupling conditions. Their structures were unambiguously verified by H-1 NMR and elemental analysis. These polymers showed high-lying LUMO energy levels of about -3.50 eV due to the less electron deficient characteristics of PTACs units. All-polymer solar cells based on these PTAC-based polymers as acceptor and P3HT as donor have been fabricated. With annealing at 100 degrees C for 15 min, P4/P3HT blends demonstrated a power conversion efficiency of up to 1.10% with a short circuit current (J(SC)) of 2.9 mA/cm(2), an open circuit voltage (V-OC) 0.92 V, and a fill factor (FF) of 0.40, illustrating that PTACs are attractive candidates for solar cells. (C) 2013 Elsevier Ltd. All rights reserved. |
语种 | 英语 |
出版者 | ELSEVIER SCI LTD |
WOS记录号 | WOS:000327560200073 |
内容类型 | 期刊论文 |
源URL | [http://ir.iccas.ac.cn/handle/121111/53873] ![]() |
专题 | 中国科学院化学研究所 |
通讯作者 | Jiang, Wei |
作者单位 | 1.Chinese Acad Sci, Inst Chem, Key Lab Organ Solids, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 3.Peking Univ, Beijing Natl Lab Mol Sci, Key Lab Bioorgan Chem & Mol Engn, Minist Educ,Coll Chem & Mol Engn, Beijing 100871, Peoples R China |
推荐引用方式 GB/T 7714 | Kang, Hongwei,Zheng, Yu-Qing,Jiang, Wei,et al. All-polymer solar cells based on PTACs/P3HT blends with large open-circuit voltage[J]. DYES AND PIGMENTS,2013,99(3):1065-1071. |
APA | Kang, Hongwei.,Zheng, Yu-Qing.,Jiang, Wei.,Xiao, Chengyi.,Wang, Jie-Yu.,...&Wang, Zhaohui.(2013).All-polymer solar cells based on PTACs/P3HT blends with large open-circuit voltage.DYES AND PIGMENTS,99(3),1065-1071. |
MLA | Kang, Hongwei,et al."All-polymer solar cells based on PTACs/P3HT blends with large open-circuit voltage".DYES AND PIGMENTS 99.3(2013):1065-1071. |
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