A novel cuprous ethylenetetrathiolate coordination polymer: Structure characterization, thermoelectric property optimization and a bulk thermogenerator demonstration

doi:10.1016/j.synthmet.2014.03.024

CORC > 化学研究所 > 中国科学院化学研究所

	A novel cuprous ethylenetetrathiolate coordination polymer: Structure characterization, thermoelectric property optimization and a bulk thermogenerator demonstration
	Sheng, Peng 1,2; Sun, Yimeng 1,2; Jiao, Fei 1,2; Di, Chongan 1; Xu, Wei 1; Zhu, Daoben 1
刊名	SYNTHETIC METALS
	2014-07-01
卷号	193 页码:1-7
关键词	Thermoelectric Thermogenerator Bulk Organic Thermoelectric Material Cu(i)-ethylenetetrathiolate
ISSN号	0379-6779
DOI	10.1016/j.synthmet.2014.03.024
英文摘要	A kind of bulk organic thermoelectric material namely Cu(I)-ethylenetetrathiolate was synthesized, and its thermoelectric properties were optimized using chemical oxidation and reduction. Both X-ray absorption fine structure and X-ray photoelectron spectroscopy techniques were used to characterize the complex. The material showed p-type property and the best thermoelectric properties were achieved with a power factor of 118.2 mu Wm(-1) K-2 and a ZT of 0.060 at 400K. A thermogenerator based on this material and n-type poly[K-x(Ni-ethylenetetrathiolate)] had an open voltage of 1.51 V and a short current of 2.71 mA under a temperature difference of 60 K. The maximum power output exceeded 1 mW, which is the best performance of the thermoelectric modules based on organic thermoelectric materials. The thermogenerator could power a liquid crystal display calculator, which shed light on the practical use of organic thermoelectric materials. (C) 2014 Elsevier B.V. All rights reserved.
语种	英语
出版者	ELSEVIER SCIENCE SA
WOS记录号	WOS:000337854600001
内容类型	期刊论文
源URL	[http://ir.iccas.ac.cn/handle/121111/52711]
专题	中国科学院化学研究所
通讯作者	Xu, Wei
作者单位	1.Chinese Acad Sci, Beijing Natl Lab Mol Sci, Key Lab Organ Solids, Inst Chem, Beijing 100190, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
推荐引用方式 GB/T 7714	Sheng, Peng,Sun, Yimeng,Jiao, Fei,et al. A novel cuprous ethylenetetrathiolate coordination polymer: Structure characterization, thermoelectric property optimization and a bulk thermogenerator demonstration[J]. SYNTHETIC METALS,2014,193:1-7.
APA	Sheng, Peng,Sun, Yimeng,Jiao, Fei,Di, Chongan,Xu, Wei,&Zhu, Daoben.(2014).A novel cuprous ethylenetetrathiolate coordination polymer: Structure characterization, thermoelectric property optimization and a bulk thermogenerator demonstration.SYNTHETIC METALS,193,1-7.
MLA	Sheng, Peng,et al."A novel cuprous ethylenetetrathiolate coordination polymer: Structure characterization, thermoelectric property optimization and a bulk thermogenerator demonstration".SYNTHETIC METALS 193(2014):1-7.