Vectorial Diffusion for Facile Solution-Processed Self-Assembly of Insoluble Semiconductors: A Case Study on Metal Phthalocyanines | |
Wang, Chengliang1,2; Fang, Yaoguo1,2; Wen, Liaoyong1,2; Zhou, Min1,2; Xu, Yang1,2; Zhao, Huaping1,2; De Cola, Luisa3; Hu, Wenping4; Lei, Yong1,2 | |
刊名 | CHEMISTRY-A EUROPEAN JOURNAL
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2014-08-25 | |
卷号 | 20期号:35页码:10990-10995 |
关键词 | Organic Semiconductors Phthalocyanine Self-assembly Solution Processing Vectorial Diffusion |
ISSN号 | 0947-6539 |
DOI | 10.1002/chem.201403702 |
英文摘要 | Solution processibility is one of the most intriguing properties of organic semiconductors. However, it is difficult to find a suitable solvent and solution process for most semiconductors. For example, metal phthalocyanines (MPcs) are only soluble in non-volatile solvents, which prevent their applications from solution process. For the first time, vectorial diffusion is utilized for solution processing of MPcs. The obtained large F16CuPc and alpha-phase CuPc crystals and the efficient phase separation of them suggest the vectorial diffusion process is as slow as a self-assembly process, which is helpful to yield large crystals and purify the semiconductors. This method, which only uses common commercial solvents without any complex and expensive instruments and hightemperature operation, provides a facile approach for purification of organic semiconductors and growth of their crystals in large quantities. |
语种 | 英语 |
出版者 | WILEY-V C H VERLAG GMBH |
WOS记录号 | WOS:000340902800017 |
内容类型 | 期刊论文 |
源URL | [http://ir.iccas.ac.cn/handle/121111/52709] ![]() |
专题 | 中国科学院化学研究所 |
通讯作者 | De Cola, Luisa |
作者单位 | 1.Tech Univ Ilmenau, Inst Phys, D-98693 Ilmenau, Germany 2.Tech Univ Ilmenau, IMN MacroNano, D-98693 Ilmenau, Germany 3.Univ Strasbourg, F-67083 Strasbourg, France 4.Chinese Acad Sci, Beijing Natl Lab Mol Sci, Key Lab Organ Solids, Inst Chem, Beijing 100190, Peoples R China |
推荐引用方式 GB/T 7714 | Wang, Chengliang,Fang, Yaoguo,Wen, Liaoyong,et al. Vectorial Diffusion for Facile Solution-Processed Self-Assembly of Insoluble Semiconductors: A Case Study on Metal Phthalocyanines[J]. CHEMISTRY-A EUROPEAN JOURNAL,2014,20(35):10990-10995. |
APA | Wang, Chengliang.,Fang, Yaoguo.,Wen, Liaoyong.,Zhou, Min.,Xu, Yang.,...&Lei, Yong.(2014).Vectorial Diffusion for Facile Solution-Processed Self-Assembly of Insoluble Semiconductors: A Case Study on Metal Phthalocyanines.CHEMISTRY-A EUROPEAN JOURNAL,20(35),10990-10995. |
MLA | Wang, Chengliang,et al."Vectorial Diffusion for Facile Solution-Processed Self-Assembly of Insoluble Semiconductors: A Case Study on Metal Phthalocyanines".CHEMISTRY-A EUROPEAN JOURNAL 20.35(2014):10990-10995. |
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