Vectorial Diffusion for Facile Solution-Processed Self-Assembly of Insoluble Semiconductors: A Case Study on Metal Phthalocyanines

doi:10.1002/chem.201403702

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	Vectorial Diffusion for Facile Solution-Processed Self-Assembly of Insoluble Semiconductors: A Case Study on Metal Phthalocyanines
	Wang, Chengliang 1,2; Fang, Yaoguo 1,2; Wen, Liaoyong 1,2; Zhou, Min 1,2; Xu, Yang 1,2; Zhao, Huaping 1,2; De Cola, Luisa 3; Hu, Wenping 4; Lei, Yong 1,2
刊名	CHEMISTRY-A EUROPEAN JOURNAL
	2014-08-25
卷号	20 期号:35 页码:10990-10995
关键词	Organic Semiconductors Phthalocyanine Self-assembly Solution Processing Vectorial Diffusion
ISSN号	0947-6539
DOI	10.1002/chem.201403702
英文摘要	Solution processibility is one of the most intriguing properties of organic semiconductors. However, it is difficult to find a suitable solvent and solution process for most semiconductors. For example, metal phthalocyanines (MPcs) are only soluble in non-volatile solvents, which prevent their applications from solution process. For the first time, vectorial diffusion is utilized for solution processing of MPcs. The obtained large F16CuPc and alpha-phase CuPc crystals and the efficient phase separation of them suggest the vectorial diffusion process is as slow as a self-assembly process, which is helpful to yield large crystals and purify the semiconductors. This method, which only uses common commercial solvents without any complex and expensive instruments and hightemperature operation, provides a facile approach for purification of organic semiconductors and growth of their crystals in large quantities.
语种	英语
出版者	WILEY-V C H VERLAG GMBH
WOS记录号	WOS:000340902800017
内容类型	期刊论文
源URL	[http://ir.iccas.ac.cn/handle/121111/52709]
专题	中国科学院化学研究所
通讯作者	De Cola, Luisa
作者单位	1.Tech Univ Ilmenau, Inst Phys, D-98693 Ilmenau, Germany 2.Tech Univ Ilmenau, IMN MacroNano, D-98693 Ilmenau, Germany 3.Univ Strasbourg, F-67083 Strasbourg, France 4.Chinese Acad Sci, Beijing Natl Lab Mol Sci, Key Lab Organ Solids, Inst Chem, Beijing 100190, Peoples R China
推荐引用方式 GB/T 7714	Wang, Chengliang,Fang, Yaoguo,Wen, Liaoyong,et al. Vectorial Diffusion for Facile Solution-Processed Self-Assembly of Insoluble Semiconductors: A Case Study on Metal Phthalocyanines[J]. CHEMISTRY-A EUROPEAN JOURNAL,2014,20(35):10990-10995.
APA	Wang, Chengliang.,Fang, Yaoguo.,Wen, Liaoyong.,Zhou, Min.,Xu, Yang.,...&Lei, Yong.(2014).Vectorial Diffusion for Facile Solution-Processed Self-Assembly of Insoluble Semiconductors: A Case Study on Metal Phthalocyanines.CHEMISTRY-A EUROPEAN JOURNAL,20(35),10990-10995.
MLA	Wang, Chengliang,et al."Vectorial Diffusion for Facile Solution-Processed Self-Assembly of Insoluble Semiconductors: A Case Study on Metal Phthalocyanines".CHEMISTRY-A EUROPEAN JOURNAL 20.35(2014):10990-10995.