Palladium-Catalyzed Intramolecular Reductive Cross-Coupling of Csp(2)-Csp(3) Bond Formation

doi:10.1002/chem.201403093

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	Palladium-Catalyzed Intramolecular Reductive Cross-Coupling of Csp(2)-Csp(3) Bond Formation
	Liu, Hui 1,2; Wei, Jianpeng 1; Qiao, Zongjun 1; Fu, Yana 1; Jiang, Xuefeng 1,3,4
刊名	CHEMISTRY-A EUROPEAN JOURNAL
	2014-07-01
卷号	20 期号:27 页码:8308-8313
关键词	Catalysis C-c Bond Formation Cross-coupling Csp(3)-x Bond Palladium
ISSN号	0947-6539
DOI	10.1002/chem.201403093
英文摘要	A Pd-catalyzed efficient reductive cross-coupling reaction without metallic reductant to construct a Csp(2)-Csp(3) bond has been reported. A Pd-IV complex was proposed to be a key intermediate, which subsequently went through double oxidative addition and double reductive elimination to produce the cross-coupling products by involving Pd-0/II/IV in one transformation. The oxidative addition from Pd-II to Pd-IV was partially demonstrated to be a radical process by self-oxidation of substrate without additional oxidants. Furthermore, the solvent was proved to be the reductant for this transformation through XPS analysis.
语种	英语
出版者	WILEY-V C H VERLAG GMBH
WOS记录号	WOS:000338019300012
内容类型	期刊论文
源URL	[http://ir.iccas.ac.cn/handle/121111/52489]
专题	中国科学院化学研究所
通讯作者	Jiang, Xuefeng
作者单位	1.E China Normal Univ, Dept Chem, Shanghai Key Lab Green Chem & Chem Proc, Shanghai 200062, Peoples R China 2.Shandong Univ Technol, Sch Chem Engn, Zibo 255049, Peoples R China 3.Peking Univ, BNLMS, Beijing, Peoples R China 4.Nankai Univ, State Key Lab Elementoorgan Chem, Tianjin, Peoples R China
推荐引用方式 GB/T 7714	Liu, Hui,Wei, Jianpeng,Qiao, Zongjun,et al. Palladium-Catalyzed Intramolecular Reductive Cross-Coupling of Csp(2)-Csp(3) Bond Formation[J]. CHEMISTRY-A EUROPEAN JOURNAL,2014,20(27):8308-8313.
APA	Liu, Hui,Wei, Jianpeng,Qiao, Zongjun,Fu, Yana,&Jiang, Xuefeng.(2014).Palladium-Catalyzed Intramolecular Reductive Cross-Coupling of Csp(2)-Csp(3) Bond Formation.CHEMISTRY-A EUROPEAN JOURNAL,20(27),8308-8313.
MLA	Liu, Hui,et al."Palladium-Catalyzed Intramolecular Reductive Cross-Coupling of Csp(2)-Csp(3) Bond Formation".CHEMISTRY-A EUROPEAN JOURNAL 20.27(2014):8308-8313.