Integrated Catalytic Process to Directly Convert Furfural to Levulinate Ester with High Selectivity

doi:10.1002/cssc.201300542

CORC > 化学研究所 > 中国科学院化学研究所

	Integrated Catalytic Process to Directly Convert Furfural to Levulinate Ester with High Selectivity
	Chen, Bingfeng 1,2; Li, Fengbo 1; Huang, Zhijun 1; Lu, Tao 1,2; Yuan, Yin 1,2; Yuan, Guoqing 1
刊名	CHEMSUSCHEM
	2014
卷号	7 期号:1 页码:202-209
关键词	Biomass Heterogeneous Catalysis Hydrogenation Nanoparticles Renewable Resources
ISSN号	1864-5631
DOI	10.1002/cssc.201300542
英文摘要	Levulinic acid is an important platform molecule from biomass-based renewable resources. A sustainable manufacturing process for this chemical and its derivatives is the enabling factor to harness the renewable resource. An integrated catalytic process to directly convert furfural to levulinate ester was developed based on a bifunctional catalyst of Pt nanoparticles supported on a ZrNb binary phosphate solid acid. The hydrogenation of furfural and the following alcoholysis of furfuryl alcohol were performed over this catalyst in a one-pot conversion model. Mesoporous ZrNb binary phosphate was synthesized by a sol-gel method and had a high surface area of 170.1 m(2)g(-1) and a large average pore size of around 8.0 nm. Pt nanoparticles remained in a monodisperse state on the support, and the reaction over Pt/ZrNbPO4 (Pt loading: 2.0 wt%; Zr/Nb, 1:1) gave a very high selectivity to levulinate derivatives (91% in total). The sustainability of this conversion was greatly improved by the process intensification based on the new catalyst, mild reaction conditions, cost abatement in separation and purification, and utilization of green reagents and solvents.
语种	英语
出版者	WILEY-V C H VERLAG GMBH
WOS记录号	WOS:000336802400024
内容类型	期刊论文
源URL	[http://ir.iccas.ac.cn/handle/121111/52343]
专题	中国科学院化学研究所
通讯作者	Li, Fengbo
作者单位	1.Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, Key Lab Green Printing, Beijing 100080, Peoples R China 2.Univ Chinese Acad Sci, Beijing 10049, Peoples R China
推荐引用方式 GB/T 7714	Chen, Bingfeng,Li, Fengbo,Huang, Zhijun,et al. Integrated Catalytic Process to Directly Convert Furfural to Levulinate Ester with High Selectivity[J]. CHEMSUSCHEM,2014,7(1):202-209.
APA	Chen, Bingfeng,Li, Fengbo,Huang, Zhijun,Lu, Tao,Yuan, Yin,&Yuan, Guoqing.(2014).Integrated Catalytic Process to Directly Convert Furfural to Levulinate Ester with High Selectivity.CHEMSUSCHEM,7(1),202-209.
MLA	Chen, Bingfeng,et al."Integrated Catalytic Process to Directly Convert Furfural to Levulinate Ester with High Selectivity".CHEMSUSCHEM 7.1(2014):202-209.