One-pot synthesis of tyrosine-stabilized fluorescent gold nanoclusters and their application as turn-on sensors for Al3+ ions and turn-off sensors for Fe3+ ions

doi:10.1039/c4ay01137f

CORC > 化学研究所 > 中国科学院化学研究所

	One-pot synthesis of tyrosine-stabilized fluorescent gold nanoclusters and their application as turn-on sensors for Al3+ ions and turn-off sensors for Fe3+ ions
	Mu, Xiaoyu 1,2; Qi, Li 1; Qiao, Juan 1; Ma, Huimin 1
刊名	ANALYTICAL METHODS
	2014-08-21
卷号	6 期号:16 页码:6445-6451
ISSN号	1759-9660
DOI	10.1039/c4ay01137f
英文摘要	The simplicity of the one-pot green synthesis routine and the capability of surface modification of various bioactive molecules make gold nanoclusters (Au NCs) highly suitable as scaffolds for the construction of novel chemical and biological sensors. In this work, we report a novel strategy to prepare amino acid stabilized fluorescent Au NCs via a green one-pot process. The obtained Au NCs possessed light green fluorescence with maximum emission at 498 nm and their quantum yield (QY) was evaluated to be 1.68%. Subsequently, the developed fluorescent Au NC biosensor allowed sensitive and selective detection of Fe3+ ions based on fluorescence quenching with a detection limit of 0.2 mu M and Al3+ ions based on enhanced fluorescence with a detection limit of 0.3 mu M, respectively. Furthermore, we testified the feasibility of applying this fluorescent probe for real sample analysis through the detection of Al3+ ions and Fe3+ ions in lake water, pond water and tap water. These results indicated that the as-prepared Au NCs had great potential to be developed as the favorable sensor for detection of metal ions in real samples.
语种	英语
出版者	ROYAL SOC CHEMISTRY
WOS记录号	WOS:000340320300035
内容类型	期刊论文
源URL	[http://ir.iccas.ac.cn/handle/121111/52155]
专题	中国科学院化学研究所
通讯作者	Qi, Li
作者单位	1.Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, Key Lab Analyt Chem Living Biosyst, Beijing 100190, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
推荐引用方式 GB/T 7714	Mu, Xiaoyu,Qi, Li,Qiao, Juan,et al. One-pot synthesis of tyrosine-stabilized fluorescent gold nanoclusters and their application as turn-on sensors for Al3+ ions and turn-off sensors for Fe3+ ions[J]. ANALYTICAL METHODS,2014,6(16):6445-6451.
APA	Mu, Xiaoyu,Qi, Li,Qiao, Juan,&Ma, Huimin.(2014).One-pot synthesis of tyrosine-stabilized fluorescent gold nanoclusters and their application as turn-on sensors for Al3+ ions and turn-off sensors for Fe3+ ions.ANALYTICAL METHODS,6(16),6445-6451.
MLA	Mu, Xiaoyu,et al."One-pot synthesis of tyrosine-stabilized fluorescent gold nanoclusters and their application as turn-on sensors for Al3+ ions and turn-off sensors for Fe3+ ions".ANALYTICAL METHODS 6.16(2014):6445-6451.