Nanostructured TiO2 modified with acetohydrazide zinc porphyrin well-arrays for supramolecular solar cells | |
Cao, Jing1; Hu, Dong-Cheng1; Liu, Jia-Cheng1; Li, Ren-Zhi2; Jin, Neng-Zhi3 | |
刊名 | ORGANIC ELECTRONICS
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2014-02-01 | |
卷号 | 15期号:2页码:509-516 |
关键词 | Self-assembly Zinc Porphyrin Solar Cell |
ISSN号 | 1566-1199 |
DOI | 10.1016/j.orgel.2013.12.004 |
英文摘要 | In this work, employing the metal-mediated assembling strategy for organizing acetohydrazide zinc porphyrin (ZnP) and different organic acid (Ai) ligands on the nanostructured TiO2 electrode surfaces have been prepared, wherein the ZnP and Ai units are bound by a series of differently bivalent metal ions (M, M = Mn2+, Co2+, Ni2+, Cu2+, Zn2+, Cd2+ and Hg2+), resulting in a ZnP-M-Ai assembled approach. The photovoltaic performances of these assemblies-sensitized solar cells were performed under irradiance of 100mWcm (2) AM 1.5G sunlight. A significantly improved conversion efficiency of ZnP-Mn-A5 and ZnP-Cd-A5 devices occurs, indicating well-ordered arrangements of ZnP molecules on the TiO2 electrode surfaces for ZnP-Mn-A5 and ZnP-Cd-A5, where A5 is a pyridine-monocarboxylic acid ligand bearing longer arm. The results were also verified by the HOMO-LUMO gaps, UV-vis and fluorescence spectra. (C) 2013 Elsevier B.V. All rights reserved. |
语种 | 英语 |
出版者 | ELSEVIER SCIENCE BV |
WOS记录号 | WOS:000329974500021 |
内容类型 | 期刊论文 |
源URL | [http://ir.iccas.ac.cn/handle/121111/52151] ![]() |
专题 | 中国科学院化学研究所 |
通讯作者 | Hu, Dong-Cheng |
作者单位 | 1.Northwest Normal Univ, Coll Chem & Chem Engn,Key Lab Ecoenvironment Rela, Key Lab Bioelectrochem & Environm Anal Gansu Prov, Minist Educ,Key Lab Polymer Mat Gansu Prov, Lanzhou 730070, Peoples R China 2.Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China 3.Gansu Comp Ctr, Lanzhou 730030, Peoples R China |
推荐引用方式 GB/T 7714 | Cao, Jing,Hu, Dong-Cheng,Liu, Jia-Cheng,et al. Nanostructured TiO2 modified with acetohydrazide zinc porphyrin well-arrays for supramolecular solar cells[J]. ORGANIC ELECTRONICS,2014,15(2):509-516. |
APA | Cao, Jing,Hu, Dong-Cheng,Liu, Jia-Cheng,Li, Ren-Zhi,&Jin, Neng-Zhi.(2014).Nanostructured TiO2 modified with acetohydrazide zinc porphyrin well-arrays for supramolecular solar cells.ORGANIC ELECTRONICS,15(2),509-516. |
MLA | Cao, Jing,et al."Nanostructured TiO2 modified with acetohydrazide zinc porphyrin well-arrays for supramolecular solar cells".ORGANIC ELECTRONICS 15.2(2014):509-516. |
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