Discovery of a silicon-based ferrimagnetic wheel structure in VxSi12- (x=1-3) clusters: photoelectron spectroscopy and density functional theory investigation

doi:10.1039/c4nr03130j

CORC > 化学研究所 > 中国科学院化学研究所

	Discovery of a silicon-based ferrimagnetic wheel structure in VxSi12- (x=1-3) clusters: photoelectron spectroscopy and density functional theory investigation
	Huang, Xiaoming 1; Xu, Hong-Guang 2; Lu, Shengjie 2; Su, Yan 1; King, R. B.3,4; Zhao, Jijun 1,5; Zheng, Weijun 2
刊名	NANOSCALE
	2014
卷号	6 期号:24 页码:14617-14621
ISSN号	2040-3364
DOI	10.1039/c4nr03130j
英文摘要	Our studies show that VSi12- adopts a V-centered hexagonal prism with a singlet spin state. The addition of the second V atom leads to a capped hexagonal antiprism for V2Si12- in a doublet spin state. Most interestingly, V3Si12- exhibits a ferrimagnetic, bicapped hexagonal antiprism wheel-like structure with a total spin of 4 mu(B).
语种	英语
出版者	ROYAL SOC CHEMISTRY
WOS记录号	WOS:000345458200002
内容类型	期刊论文
源URL	[http://ir.iccas.ac.cn/handle/121111/52131]
专题	中国科学院化学研究所
通讯作者	Zhao, Jijun
作者单位	1.Dalian Univ Technol, Minist Educ, Key Lab Mat Modificat Laser Ion & Electron Beams, Dalian 116024, Peoples R China 2.Chinese Acad Sci, Inst Chem, State Key Lab Mol React Dynam, Beijing 100190, Peoples R China 3.Univ Georgia, Dept Chem, Athens, GA 30602 USA 4.Univ Georgia, Ctr Computat Chem, Athens, GA 30602 USA 5.Beijing Computat Sci Res Ctr, Beijing 100089, Peoples R China
推荐引用方式 GB/T 7714	Huang, Xiaoming,Xu, Hong-Guang,Lu, Shengjie,et al. Discovery of a silicon-based ferrimagnetic wheel structure in VxSi12- (x=1-3) clusters: photoelectron spectroscopy and density functional theory investigation[J]. NANOSCALE,2014,6(24):14617-14621.
APA	Huang, Xiaoming.,Xu, Hong-Guang.,Lu, Shengjie.,Su, Yan.,King, R. B..,...&Zheng, Weijun.(2014).Discovery of a silicon-based ferrimagnetic wheel structure in VxSi12- (x=1-3) clusters: photoelectron spectroscopy and density functional theory investigation.NANOSCALE,6(24),14617-14621.
MLA	Huang, Xiaoming,et al."Discovery of a silicon-based ferrimagnetic wheel structure in VxSi12- (x=1-3) clusters: photoelectron spectroscopy and density functional theory investigation".NANOSCALE 6.24(2014):14617-14621.