Solvent property induced morphological changes of ABA amphiphilic triblock copolymer micelles in dilute solution: A self-consistent field simulation study

doi:10.1007/s10118-014-1529-3

CORC > 化学研究所 > 中国科学院化学研究所

	Solvent property induced morphological changes of ABA amphiphilic triblock copolymer micelles in dilute solution: A self-consistent field simulation study
	Fan, Juan-juan 1; Han, Yuan-yuan 2; Cui, Jie 2
刊名	CHINESE JOURNAL OF POLYMER SCIENCE
	2014-12-01
卷号	32 期号:12 页码:1704-1713
关键词	Solvent Property Triblock Copolymer Self-consistent Field Simulation
ISSN号	0256-7679
DOI	10.1007/s10118-014-1529-3
英文摘要	The morphological changes of ABA amphiphilic triblock copolymer micelles in dilute solution were systematically studied by tuning the solvent property using self-consistent field simulation. The solvent property was tuned by changing the Flory-Huggins interaction parameters between each type of blocks and solvent, respectively. The simulation results show that by changing the solvent properties, a series of micelle morphologies such as vesicle, cage-like, ring-shaped, rod-like and spherical micelle morphologies can be obtained. Variations of the free energy of the solution system and the surface area of micelles with the Flory-Huggins interaction parameters were calculated to better understand the effect of solvent property on micelle morphologies. In addition, a phase diagram showing the morphological changes of micelles with the Flory-Huggins interaction parameters is provided.
语种	英语
出版者	SPRINGER
WOS记录号	WOS:000344542100013
内容类型	期刊论文
源URL	[http://ir.iccas.ac.cn/handle/121111/51651]
专题	中国科学院化学研究所
通讯作者	Cui, Jie
作者单位	1.Jilin Agr Univ, Coll Informat Technol, Changchun 130118, Peoples R China 2.Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China
推荐引用方式 GB/T 7714	Fan, Juan-juan,Han, Yuan-yuan,Cui, Jie. Solvent property induced morphological changes of ABA amphiphilic triblock copolymer micelles in dilute solution: A self-consistent field simulation study[J]. CHINESE JOURNAL OF POLYMER SCIENCE,2014,32(12):1704-1713.
APA	Fan, Juan-juan,Han, Yuan-yuan,&Cui, Jie.(2014).Solvent property induced morphological changes of ABA amphiphilic triblock copolymer micelles in dilute solution: A self-consistent field simulation study.CHINESE JOURNAL OF POLYMER SCIENCE,32(12),1704-1713.
MLA	Fan, Juan-juan,et al."Solvent property induced morphological changes of ABA amphiphilic triblock copolymer micelles in dilute solution: A self-consistent field simulation study".CHINESE JOURNAL OF POLYMER SCIENCE 32.12(2014):1704-1713.