Solvent property induced morphological changes of ABA amphiphilic triblock copolymer micelles in dilute solution: A self-consistent field simulation study | |
Fan, Juan-juan1; Han, Yuan-yuan2; Cui, Jie2 | |
刊名 | CHINESE JOURNAL OF POLYMER SCIENCE
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2014-12-01 | |
卷号 | 32期号:12页码:1704-1713 |
关键词 | Solvent Property Triblock Copolymer Self-consistent Field Simulation |
ISSN号 | 0256-7679 |
DOI | 10.1007/s10118-014-1529-3 |
英文摘要 | The morphological changes of ABA amphiphilic triblock copolymer micelles in dilute solution were systematically studied by tuning the solvent property using self-consistent field simulation. The solvent property was tuned by changing the Flory-Huggins interaction parameters between each type of blocks and solvent, respectively. The simulation results show that by changing the solvent properties, a series of micelle morphologies such as vesicle, cage-like, ring-shaped, rod-like and spherical micelle morphologies can be obtained. Variations of the free energy of the solution system and the surface area of micelles with the Flory-Huggins interaction parameters were calculated to better understand the effect of solvent property on micelle morphologies. In addition, a phase diagram showing the morphological changes of micelles with the Flory-Huggins interaction parameters is provided. |
语种 | 英语 |
出版者 | SPRINGER |
WOS记录号 | WOS:000344542100013 |
内容类型 | 期刊论文 |
源URL | [http://ir.iccas.ac.cn/handle/121111/51651] ![]() |
专题 | 中国科学院化学研究所 |
通讯作者 | Cui, Jie |
作者单位 | 1.Jilin Agr Univ, Coll Informat Technol, Changchun 130118, Peoples R China 2.Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China |
推荐引用方式 GB/T 7714 | Fan, Juan-juan,Han, Yuan-yuan,Cui, Jie. Solvent property induced morphological changes of ABA amphiphilic triblock copolymer micelles in dilute solution: A self-consistent field simulation study[J]. CHINESE JOURNAL OF POLYMER SCIENCE,2014,32(12):1704-1713. |
APA | Fan, Juan-juan,Han, Yuan-yuan,&Cui, Jie.(2014).Solvent property induced morphological changes of ABA amphiphilic triblock copolymer micelles in dilute solution: A self-consistent field simulation study.CHINESE JOURNAL OF POLYMER SCIENCE,32(12),1704-1713. |
MLA | Fan, Juan-juan,et al."Solvent property induced morphological changes of ABA amphiphilic triblock copolymer micelles in dilute solution: A self-consistent field simulation study".CHINESE JOURNAL OF POLYMER SCIENCE 32.12(2014):1704-1713. |
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