Preparation and Application of Supramolecular Functional Materials Based on pi System

doi:10.7536/PC130939

CORC > 化学研究所 > 中国科学院化学研究所

	Preparation and Application of Supramolecular Functional Materials Based on pi System
	Xu Liang 1,2; Li Yongjun 1; Li Yuliang 1
刊名	PROGRESS IN CHEMISTRY
	2014-04-01
卷号	26 期号:4 页码:487-501
关键词	Pi System Supramolecular Chemistry Preparation Application
ISSN号	1005-281X
DOI	10.7536/PC130939
英文摘要	Recent years have witnessed a rapid development of the preparation methods for aggregation structures and have witnessed a continuous expansion of the application areas, which afford the opportunity to construct molecular devices with smaller size, stronger function and better performance. The organic conjugated molecules based on pi system have attracted an increasing attention as a novel unit for the building of nanostructures. In this paper, beginning with the introduction of the concept and characteristic of nanomaterials, we discuss the construction methods for supramolecular functional materials based on organic pi-conjugated and inorganic/organic hybrid systems. For organic pi-conjugated system, the methods include vapor deposition, template and classic self-assembly. For inorganic/organic hybrid system, the methods include sol-gel, intercalation, blending, template and supramolecular self-assembly. Among these methods, we focus on the classic self-assembly one for organic system. In the process of self-assembly, several driving forces have important influence on the aggregation morphologies, including pi-pi stacking, hydrogen bonding, electrostatic interaction, dipole-dipole interaction, metal coordination, hydrophilic and hydrophobic interactions. Although in this process, one or two driving force predominate, several driving forces are involved actually. On the basis of the preparation of nanomaterials, we discuss the construction of functional molecular devices and their wide applications in the fields of field emission, photoelectric detection, solar cells, sensors, nonlinear optical and optical waveguide materials.
语种	英语
出版者	CHINESE ACAD SCIENCES
WOS记录号	WOS:000335279700001
内容类型	期刊论文
源URL	[http://ir.iccas.ac.cn/handle/121111/51297]
专题	中国科学院化学研究所
通讯作者	Li Yongjun
作者单位	1.Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, Key Lab Organ Solid, Beijing 100190, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
推荐引用方式 GB/T 7714	Xu Liang,Li Yongjun,Li Yuliang. Preparation and Application of Supramolecular Functional Materials Based on pi System[J]. PROGRESS IN CHEMISTRY,2014,26(4):487-501.
APA	Xu Liang,Li Yongjun,&Li Yuliang.(2014).Preparation and Application of Supramolecular Functional Materials Based on pi System.PROGRESS IN CHEMISTRY,26(4),487-501.
MLA	Xu Liang,et al."Preparation and Application of Supramolecular Functional Materials Based on pi System".PROGRESS IN CHEMISTRY 26.4(2014):487-501.