Synthesis and Reactivity Studies of a Tin(II) Corrole Complex

doi:10.1021/ic501103c

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	Synthesis and Reactivity Studies of a Tin(II) Corrole Complex
	Yun, Lin 1; Vazquez-Lima, Hugo 3,4; Fang, Huayi 1; Yao, Zhengmin 1; Geisberger, Georg 2; Dietl, Christian 2; Ghosh, Abhik 3,4; Brothers, Penelope J.2; Fu, Xuefeng 1
刊名	INORGANIC CHEMISTRY
	2014-07-07
卷号	53 期号:13 页码:7047-7054
ISSN号	0020-1669
DOI	10.1021/ic501103c
英文摘要	A series of tris(pentafluorophenyl)corrole (TPFC) tin(IV) and tin(II) complexes were prepared and studied by various characterization techniques including H-1, F-19, and Sn-119 NMR and UV-vis spectroscopy, mass spectrometry, and single-crystal X-ray diffraction. The unusual 4-coordinate, monomeric, divalent tin(II) complex [(TPFC)-Sn-II](-) (2a) showed highly efficient reactivity toward alkenes and alkyl halides via a nudeophilic addition pathway leading to the quantitative formation of alkyl stannyl corrole compounds. DFT calculations confirmed the divalent nature of the tin center in 2a, and an NBO analysis showed about 99.99% Sn lone pair character, of which 83.6% was Sn 5s and 16.35% was Sn 5p character.
语种	英语
出版者	AMER CHEMICAL SOC
WOS记录号	WOS:000338748100073
内容类型	期刊论文
源URL	[http://ir.iccas.ac.cn/handle/121111/50633]
专题	中国科学院化学研究所
通讯作者	Ghosh, Abhik
作者单位	1.Peking Univ, Beijing Natl Lab Mol Sci, Coll Chem & Mol Engn, Beijing 100871, Peoples R China 2.Univ Auckland, Sch Chem Sci, Auckland 1142, New Zealand 3.UiT Arctic Univ Norway, Dept Chem, N-9037 Tromso, Norway 4.UiT Arctic Univ Norway, Ctr Theoret & Computat Chem, N-9037 Tromso, Norway
推荐引用方式 GB/T 7714	Yun, Lin,Vazquez-Lima, Hugo,Fang, Huayi,et al. Synthesis and Reactivity Studies of a Tin(II) Corrole Complex[J]. INORGANIC CHEMISTRY,2014,53(13):7047-7054.
APA	Yun, Lin.,Vazquez-Lima, Hugo.,Fang, Huayi.,Yao, Zhengmin.,Geisberger, Georg.,...&Fu, Xuefeng.(2014).Synthesis and Reactivity Studies of a Tin(II) Corrole Complex.INORGANIC CHEMISTRY,53(13),7047-7054.
MLA	Yun, Lin,et al."Synthesis and Reactivity Studies of a Tin(II) Corrole Complex".INORGANIC CHEMISTRY 53.13(2014):7047-7054.