Self-Assembly of Pyridinium-Functionalized Anthracenes: Molecular-Skeleton-Directed Formation of Microsheets and Microtubes | |
Hu, Jun1; Wang, Peiyi2; Lin, Yuan3; Zhang, Jidong3; Smith, Mark1; Pellechia, Perry J.1; Yang, Song2; Song, Baoan2; Wang, Qian1 | |
刊名 | CHEMISTRY-A EUROPEAN JOURNAL
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2014-06-16 | |
卷号 | 20期号:25页码:7603-7607 |
关键词 | Amphiphiles Charge Transfer Molecular Engineering Pi-pi Interactions Self-assembly |
ISSN号 | 0947-6539 |
DOI | 10.1002/chem.201402631 |
英文摘要 | Two amphiphilic regioisomers, 9-AP (1-[11-(9-anthracenylmethoxy)-11-oxoundecyl] pyridinium bromide), and 2-AP (1-[11-(2-anthracenyl methoxy)-11-oxoundecyl]-pyridinium bromide), were synthesized and their assembly behaviors were studied. Due to the anisotropic features of the anthracene structure, different substituted positions on the anthracene ring lead 9-AP and 2-AP to adapt "shaver" and "spatula"-like molecular shapes, respectively, which consequently dictate the structure of their final assemblies. While "shaver"-shaped 9-AP assembled into microsheets, driven by pi-pi interactions, "spatula"-shaped 2-AP assembled into microtubular structures, promoted primarily by charge-transfer interactions. |
语种 | 英语 |
出版者 | WILEY-V C H VERLAG GMBH |
WOS记录号 | WOS:000337637400010 |
内容类型 | 期刊论文 |
源URL | [http://ir.iccas.ac.cn/handle/121111/50425] ![]() |
专题 | 中国科学院化学研究所 |
通讯作者 | Song, Baoan |
作者单位 | 1.Univ S Carolina, Dept Chem & Biochem, Columbia, SC 29208 USA 2.Guizhou Univ, State Key Lab Breeding Base Green Pesticide & Agr, Ctr R&D Fine Chem, Guiyang 550025, Peoples R China 3.Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China |
推荐引用方式 GB/T 7714 | Hu, Jun,Wang, Peiyi,Lin, Yuan,et al. Self-Assembly of Pyridinium-Functionalized Anthracenes: Molecular-Skeleton-Directed Formation of Microsheets and Microtubes[J]. CHEMISTRY-A EUROPEAN JOURNAL,2014,20(25):7603-7607. |
APA | Hu, Jun.,Wang, Peiyi.,Lin, Yuan.,Zhang, Jidong.,Smith, Mark.,...&Wang, Qian.(2014).Self-Assembly of Pyridinium-Functionalized Anthracenes: Molecular-Skeleton-Directed Formation of Microsheets and Microtubes.CHEMISTRY-A EUROPEAN JOURNAL,20(25),7603-7607. |
MLA | Hu, Jun,et al."Self-Assembly of Pyridinium-Functionalized Anthracenes: Molecular-Skeleton-Directed Formation of Microsheets and Microtubes".CHEMISTRY-A EUROPEAN JOURNAL 20.25(2014):7603-7607. |
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