Self-Assembly of Pyridinium-Functionalized Anthracenes: Molecular-Skeleton-Directed Formation of Microsheets and Microtubes

doi:10.1002/chem.201402631

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	Self-Assembly of Pyridinium-Functionalized Anthracenes: Molecular-Skeleton-Directed Formation of Microsheets and Microtubes
	Hu, Jun 1; Wang, Peiyi 2; Lin, Yuan 3; Zhang, Jidong 3; Smith, Mark 1; Pellechia, Perry J.1; Yang, Song 2; Song, Baoan 2; Wang, Qian 1
刊名	CHEMISTRY-A EUROPEAN JOURNAL
	2014-06-16
卷号	20 期号:25 页码:7603-7607
关键词	Amphiphiles Charge Transfer Molecular Engineering Pi-pi Interactions Self-assembly
ISSN号	0947-6539
DOI	10.1002/chem.201402631
英文摘要	Two amphiphilic regioisomers, 9-AP (1-[11-(9-anthracenylmethoxy)-11-oxoundecyl] pyridinium bromide), and 2-AP (1-[11-(2-anthracenyl methoxy)-11-oxoundecyl]-pyridinium bromide), were synthesized and their assembly behaviors were studied. Due to the anisotropic features of the anthracene structure, different substituted positions on the anthracene ring lead 9-AP and 2-AP to adapt "shaver" and "spatula"-like molecular shapes, respectively, which consequently dictate the structure of their final assemblies. While "shaver"-shaped 9-AP assembled into microsheets, driven by pi-pi interactions, "spatula"-shaped 2-AP assembled into microtubular structures, promoted primarily by charge-transfer interactions.
语种	英语
出版者	WILEY-V C H VERLAG GMBH
WOS记录号	WOS:000337637400010
内容类型	期刊论文
源URL	[http://ir.iccas.ac.cn/handle/121111/50425]
专题	中国科学院化学研究所
通讯作者	Song, Baoan
作者单位	1.Univ S Carolina, Dept Chem & Biochem, Columbia, SC 29208 USA 2.Guizhou Univ, State Key Lab Breeding Base Green Pesticide & Agr, Ctr R&D Fine Chem, Guiyang 550025, Peoples R China 3.Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China
推荐引用方式 GB/T 7714	Hu, Jun,Wang, Peiyi,Lin, Yuan,et al. Self-Assembly of Pyridinium-Functionalized Anthracenes: Molecular-Skeleton-Directed Formation of Microsheets and Microtubes[J]. CHEMISTRY-A EUROPEAN JOURNAL,2014,20(25):7603-7607.
APA	Hu, Jun.,Wang, Peiyi.,Lin, Yuan.,Zhang, Jidong.,Smith, Mark.,...&Wang, Qian.(2014).Self-Assembly of Pyridinium-Functionalized Anthracenes: Molecular-Skeleton-Directed Formation of Microsheets and Microtubes.CHEMISTRY-A EUROPEAN JOURNAL,20(25),7603-7607.
MLA	Hu, Jun,et al."Self-Assembly of Pyridinium-Functionalized Anthracenes: Molecular-Skeleton-Directed Formation of Microsheets and Microtubes".CHEMISTRY-A EUROPEAN JOURNAL 20.25(2014):7603-7607.