Facile in situ syntheses of new templates and formations of three zinc phosphates

doi:10.1016/j.inoche.2014.06.025

CORC > 化学研究所 > 中国科学院化学研究所

	Facile in situ syntheses of new templates and formations of three zinc phosphates
	Wang, Guo-Ming 1; Li, Jin-Hua 1; Zhang, Xiao 1; Jiao, Ji-Qing 1; Bao, Zhen-Zhen 1; Zhao, Xiao-Meng 1; Jiang, Wen-Wen 1; Wang, Ying-Xia 2; Lin, Jian-Hua 2
刊名	INORGANIC CHEMISTRY COMMUNICATIONS
	2014-08-01
卷号	46 页码:295-300
关键词	Zinc Phosphate Crystal Structure N-alkylation In Situ Solvothermal Synthesis
ISSN号	1387-7003
DOI	10.1016/j.inoche.2014.06.025
英文摘要	Three new organically templated zinc phosphates, namely, [dmdabco][Zn-2(HPO4)(3)]center dot(H2O) (1), [tmpip](0.5) [Zn-2(HPO4)(2)(H2PO4)] (2) and [tmpip][Zn-3(HPO4)(4)] (3) (dmdabco = N,N'-dimethyl-1,4-diazabicyclo [2,2,2]octane, tmpip = N,N,N',N'-tetramethyl-piperazinium), were successfully synthesized under solvothermal reactions and structurally characterized by single-crystal X-ray diffraction. The dmdabco(2+) and tmpip(2+) templating agents were derived respectively from simple in situ N-alkylation transformations between the methanol solvent and organic cyclic aliphatic diamines, 1,4-diazabicyclo[2,2,2]octane (dabco) in 1 and 1-methylpiperazine in 2 and 3. Such direct methylation feature is unique, and quite different from conventional Eschweiler-Clarke methylation in which an excess of formic acid and formaldehyde was required. Compound 1 exhibits a 4-connected 2D (4,4) net with pentameric [Zn2(HPO4)3] clusters as secondary building units (SBUs); 2 possesses a complex double layered structure with 12-ring windows. Compound 3 has a (3, 4)-connected 3D pcu architecture with heptameric [Zn-3(HPO4)(4)] clusters as SBUs, forming intersecting 8- and 12-ring channels. (C) 2014 Elsevier B.V. All rights reserved.
语种	英语
出版者	ELSEVIER SCIENCE BV
WOS记录号	WOS:000340309500072
内容类型	期刊论文
源URL	[http://ir.iccas.ac.cn/handle/121111/50071]
专题	中国科学院化学研究所
通讯作者	Wang, Guo-Ming
作者单位	1.Qingdao Univ, Growing Base State Key Lab New Fiber & Modern Tex, Inst Hybrid Mat, Teachers Coll,Coll Chem & Chem Engn, Qingdao 266071, Shandong, Peoples R China 2.Peking Univ, Coll Chem & Mol Engn, Beijing Natl Lab Mol Sci, Beijing 100871, Peoples R China
推荐引用方式 GB/T 7714	Wang, Guo-Ming,Li, Jin-Hua,Zhang, Xiao,et al. Facile in situ syntheses of new templates and formations of three zinc phosphates[J]. INORGANIC CHEMISTRY COMMUNICATIONS,2014,46:295-300.
APA	Wang, Guo-Ming.,Li, Jin-Hua.,Zhang, Xiao.,Jiao, Ji-Qing.,Bao, Zhen-Zhen.,...&Lin, Jian-Hua.(2014).Facile in situ syntheses of new templates and formations of three zinc phosphates.INORGANIC CHEMISTRY COMMUNICATIONS,46,295-300.
MLA	Wang, Guo-Ming,et al."Facile in situ syntheses of new templates and formations of three zinc phosphates".INORGANIC CHEMISTRY COMMUNICATIONS 46(2014):295-300.