A Nanosized {Ag@Ag-12} "Molecular Windmill" Templated by Polyoxometalates Anions | |
Wang, Lei1; Yang, Weiting1; Zhu, Wei1; Guan, Xingang2; Xie, Zhigang2; Sun, Zhong-Ming1 | |
刊名 | INORGANIC CHEMISTRY |
2014-11-03 | |
卷号 | 53期号:21页码:11584-11588 |
ISSN号 | 0020-1669 |
DOI | 10.1021/ic501657p |
英文摘要 | Reaction of multidentate 5-(4-imidazol-1-yl-phenyl)-2H-tetrazole (L) ligand with Ag(I) ions in the existence of H(3)PW(1)2O(4)0 as anionic template under hydrothermal conditions results in tridecanuclear silver cluster-polyoxometalates hybrid: {Ag13L12}{PW12O40}(4).30H(2)O (1). X-ray single crystal diffraction analysis indicates that the main structural feature of 1 is a nanosized molecular windmill-shaped polynuclear Ag cluster with intriguing {M@M-12}-type cuboctahedral topology. The as-synthesized compound exhibits effective photocatalytic activity in the photodegradation of Rhodamine-B (RhB) and antibacterial activity against Escherichia coli, respectively. |
语种 | 英语 |
出版者 | AMER CHEMICAL SOC |
WOS记录号 | WOS:000344307400027 |
内容类型 | 期刊论文 |
源URL | [http://ir.iccas.ac.cn/handle/121111/50027] |
专题 | 中国科学院化学研究所 |
通讯作者 | Sun, Zhong-Ming |
作者单位 | 1.Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Rare Earth Resource Utilizat, Changchun 130022, Jilin, Peoples R China 2.Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Jilin, Peoples R China |
推荐引用方式 GB/T 7714 | Wang, Lei,Yang, Weiting,Zhu, Wei,et al. A Nanosized {Ag@Ag-12} "Molecular Windmill" Templated by Polyoxometalates Anions[J]. INORGANIC CHEMISTRY,2014,53(21):11584-11588. |
APA | Wang, Lei,Yang, Weiting,Zhu, Wei,Guan, Xingang,Xie, Zhigang,&Sun, Zhong-Ming.(2014).A Nanosized {Ag@Ag-12} "Molecular Windmill" Templated by Polyoxometalates Anions.INORGANIC CHEMISTRY,53(21),11584-11588. |
MLA | Wang, Lei,et al."A Nanosized {Ag@Ag-12} "Molecular Windmill" Templated by Polyoxometalates Anions".INORGANIC CHEMISTRY 53.21(2014):11584-11588. |
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