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Inkjet printed colloidal photonic crystal microdot with fast response induced by hydrophobic transition of poly(N-isopropyl acrylamide)
Wang, Libin1,2; Wang, Jingxia1; Huang, Yu1,2; Liu, Meijin1,2; Kuang, Minxuan1,2; Li, Yingfeng1; Jiang, Lei1; Song, Yanlin1
刊名JOURNAL OF MATERIALS CHEMISTRY
2012-10-28
卷号22期号:40页码:21405-21411
ISSN号0959-9428
DOI10.1039/c2jm33411a
英文摘要This paper presents rapid response colloidal photonic crystal (PC) microdots fabricated by inkjet printing, which demonstrate a fastest response of ca. 1.2 s to water vapor. This remarkable improvement of response rate could be attributed to the combined effects of the intrinsic small size of the inkjet microdots and the hydrophobic transition of poly(N-isopropyl acrylamide) (PNIPAm) above its lower critical solution temperature (LCST). The reversible phase transition of PNIPAm modifies the hydrophilic-hydrophobic balance of the polymer interface, which leads to the modulation of wetting states/adhesion properties of adsorbed water on the polymer segments, resulting in the remarkable improvement of response rate. Moreover, the optimal response performance (including signal strength and response sensitivity) of the printed PC microdot is achieved by the coordination of a well-ordered latex assembly and full infiltration of the responsive polymer in the latex interstices. This simple fabrication of functional colloidal PC microdots opens new avenues for the construction of advanced microanalysis and microsensing devices. In addition, improving the response rate by the phase transition of the polymer segments is promising for the creation of high-performance sensors.
语种英语
出版者ROYAL SOC CHEMISTRY
WOS记录号WOS:000309852400012
内容类型期刊论文
源URL[http://ir.iccas.ac.cn/handle/121111/49755]  
专题中国科学院化学研究所
通讯作者Wang, Jingxia
作者单位1.Chinese Acad Sci, Ctr Mol Sci, New Mat Lab, BNLMS,Key Lab Organ Solids,Inst Chem, Beijing 100190, Peoples R China
2.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China
推荐引用方式
GB/T 7714
Wang, Libin,Wang, Jingxia,Huang, Yu,et al. Inkjet printed colloidal photonic crystal microdot with fast response induced by hydrophobic transition of poly(N-isopropyl acrylamide)[J]. JOURNAL OF MATERIALS CHEMISTRY,2012,22(40):21405-21411.
APA Wang, Libin.,Wang, Jingxia.,Huang, Yu.,Liu, Meijin.,Kuang, Minxuan.,...&Song, Yanlin.(2012).Inkjet printed colloidal photonic crystal microdot with fast response induced by hydrophobic transition of poly(N-isopropyl acrylamide).JOURNAL OF MATERIALS CHEMISTRY,22(40),21405-21411.
MLA Wang, Libin,et al."Inkjet printed colloidal photonic crystal microdot with fast response induced by hydrophobic transition of poly(N-isopropyl acrylamide)".JOURNAL OF MATERIALS CHEMISTRY 22.40(2012):21405-21411.
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