2-(1-(Arylimino)ethyl)-8-arylimino-5,6,7-trihydroquinoline Iron(II) Chloride Complexes: Synthesis, Characterization, and Ethylene Polymerization Behavior

doi:10.1021/om300388m

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	2-(1-(Arylimino)ethyl)-8-arylimino-5,6,7-trihydroquinoline Iron(II) Chloride Complexes: Synthesis, Characterization, and Ethylene Polymerization Behavior
	Zhang, Wenjuan 1,2; Chai, Wenbin 1,2,3; Sun, Wen-Hua1,2 ; Hu, Xinquan 3; Redshaw, Carl 4; Hao, Xiang 1,2
刊名	ORGANOMETALLICS
	2012-07-23
卷号	31 期号:14 页码:5039-5048
ISSN号	0276-7333
DOI	10.1021/om300388m
英文摘要	The series of 2-(1-(arylimino)ethyl)-8-arylimino-5,6,7-trihydroquinolines was synthesized and fully characterized, for which data indicated two isomer forms of each due to the migration of a double bond. The corresponding iron dichloride complexes were prepared and were found to adopt distorted bipyramidal coordination geometry at iron by single-crystal X-ray diffraction studies. Upon treatment with either MAO or MMAO, all iron complex precatalysts exhibited high activities (up to 2.4 x 10(7) gPE.mol(-1)(Fe).h(-1)) toward ethylene polymerization. The influence of the nature of the ligands and reaction parameters upon the catalytic activities and properties of the polyethylene obtained has been studied.
语种	英语
出版者	AMER CHEMICAL SOC
WOS记录号	WOS:000306613600015
内容类型	期刊论文
源URL	[http://ir.iccas.ac.cn/handle/121111/49409]
专题	中国科学院化学研究所
通讯作者	Sun, Wen-Hua
作者单位	1.Chinese Acad Sci, Inst Chem, Key Lab Engn Plast, Beijing 100190, Peoples R China 2.Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China 3.Zhejiang Univ Technol, Coll Chem Engn & Mat Sci, Hangzhou 310014, Zhejiang, Peoples R China 4.Univ E Anglia, Sch Chem, Norwich NR4 7TJ, Norfolk, England
推荐引用方式 GB/T 7714	Zhang, Wenjuan,Chai, Wenbin,Sun, Wen-Hua,et al. 2-(1-(Arylimino)ethyl)-8-arylimino-5,6,7-trihydroquinoline Iron(II) Chloride Complexes: Synthesis, Characterization, and Ethylene Polymerization Behavior[J]. ORGANOMETALLICS,2012,31(14):5039-5048.
APA	Zhang, Wenjuan,Chai, Wenbin,Sun, Wen-Hua,Hu, Xinquan,Redshaw, Carl,&Hao, Xiang.(2012).2-(1-(Arylimino)ethyl)-8-arylimino-5,6,7-trihydroquinoline Iron(II) Chloride Complexes: Synthesis, Characterization, and Ethylene Polymerization Behavior.ORGANOMETALLICS,31(14),5039-5048.
MLA	Zhang, Wenjuan,et al."2-(1-(Arylimino)ethyl)-8-arylimino-5,6,7-trihydroquinoline Iron(II) Chloride Complexes: Synthesis, Characterization, and Ethylene Polymerization Behavior".ORGANOMETALLICS 31.14(2012):5039-5048.