Chelating Schiff base assisted azide-bridged Mn(II), Ni(II) and Cu(II) magnetic coordination polymers | |
Bai, Shi-Qiang1,2,3; Fang, Chen-Jie2,3,4; He, Zheng2,3; Gao, En-Qing5; Yan, Chun-Hua2,3; Hor, T. S. Andy1,6 | |
刊名 | DALTON TRANSACTIONS
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2012 | |
卷号 | 41期号:43页码:13379-13387 |
ISSN号 | 1477-9226 |
DOI | 10.1039/c2dt31186k |
英文摘要 | Four new Mn(II), Ni(II) and Cu(II) coordination polymers [Mn-2(L-1)(mu(1,1)-N-3)(2)(mu(1,3)-N-3)(2)](n) (1), [Ni(L-2)(2)(mu(1,3)-N-3)](n)(ClO4)(n) (2), [Cu(L-3)(mu(1,1)-N-3)(N-3)](n) (3) and [Cu(L-4)(mu(1,1)-N-3)(2)](n) (4) (L-1 = N, N'-bis(2-pyridylmethylene)ethane-1,2-diamine, L-2 = N-(2-pyridylmethylene)methylamine, L-3 = N-(2-pyridylmethylene)-3-pyridylamine, L-4 = N-(2-pyridylmethylene)-tbutylamine) have been synthesized and characterized by single-crystal X-ray analysis and magnetic measurements. Complex 1 indicates a stoichiometry-dependent structural change (based on Mn : L-1 : N-3 = 2 : 1 : 4 molar ratio) and consists of two-dimensional (2-D) (4,4) net layers, in which Mn(II) centers are co-bridged by single end-to-end (EE), double end-on (EO) azide and chelate-bridging L-1 ligands. Complex 2 shows a single EE azide-bridged one-dimensional (1-D) Ni(II) chain. Complexes 3 and 4 indicate single EO and double EO azide-bridged 1-D Cu(II) chains, respectively. Complex 1 exhibits weak ferromagnetism due to its intra-layer spin-canting with T-c = 20 K. Complex 2 shows an unusual intra-chain ferromagnetic coupling and spin-canting behaviour. Both complexes 3 and 4 exhibit intra-chain antiferromagnetic interactions. Magneto-structural parameters for these related complexes were also discussed. |
语种 | 英语 |
出版者 | ROYAL SOC CHEMISTRY |
WOS记录号 | WOS:000309885500022 |
内容类型 | 期刊论文 |
源URL | [http://ir.iccas.ac.cn/handle/121111/49029] ![]() |
专题 | 中国科学院化学研究所 |
通讯作者 | Bai, Shi-Qiang |
作者单位 | 1.ASTAR, Inst Mat Res & Engn, Singapore 117602, Singapore 2.Peking Univ, Coll Chem & Mol Engn, Beijing Natl Lab Mol Sci, State Key Lab Rare Earth Mat Chem & Applicat, Beijing 100871, Peoples R China 3.Peking Univ, Coll Chem & Mol Engn, PKU HKU Joint Lab Rare Earth Mat & Bioinorgan Che, Beijing 100871, Peoples R China 4.Capital Med Univ, Sch Chem Biol & Pharmaceut, Beijing 100069, Peoples R China 5.E China Normal Univ, Dept Chem, Shanghai Key Lab Green Chem & Chem Proc, Shanghai 200062, Peoples R China 6.Natl Univ Singapore, Dept Chem, Singapore 117543, Singapore |
推荐引用方式 GB/T 7714 | Bai, Shi-Qiang,Fang, Chen-Jie,He, Zheng,et al. Chelating Schiff base assisted azide-bridged Mn(II), Ni(II) and Cu(II) magnetic coordination polymers[J]. DALTON TRANSACTIONS,2012,41(43):13379-13387. |
APA | Bai, Shi-Qiang,Fang, Chen-Jie,He, Zheng,Gao, En-Qing,Yan, Chun-Hua,&Hor, T. S. Andy.(2012).Chelating Schiff base assisted azide-bridged Mn(II), Ni(II) and Cu(II) magnetic coordination polymers.DALTON TRANSACTIONS,41(43),13379-13387. |
MLA | Bai, Shi-Qiang,et al."Chelating Schiff base assisted azide-bridged Mn(II), Ni(II) and Cu(II) magnetic coordination polymers".DALTON TRANSACTIONS 41.43(2012):13379-13387. |
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