One-pot conversion of CO2 and glycerol to value-added products using propylene oxide as the coupling agent

doi:10.1039/c2gc35150a

CORC > 化学研究所 > 中国科学院化学研究所

	One-pot conversion of CO2 and glycerol to value-added products using propylene oxide as the coupling agent
	Ma, Jun; Song, Jinliang; Liu, Huizhen; Liu, Jinli; Zhang, Zhaofu; Jiang, Tao; Fan, Honglei; Han, Buxing
刊名	GREEN CHEMISTRY
	2012
卷号	14 期号:6 页码:1743-1748
ISSN号	1463-9262
DOI	10.1039/c2gc35150a
英文摘要	The effective conversion of carbon dioxide (CO2) and glycerol is an interesting topic in green chemistry. In this work, we studied the simultaneous transformation of CO2 and glycerol to value-added products using propylene oxide (PO) as coupling agent catalyzed by alkali metal halides. The effects of reaction temperature, CO2 pressure, reaction time, amount of catalyst, and PO to glycerol molar ratio on the reaction were investigated. It was discovered that the coupled catalytic reaction could produce glycerol carbonate (GC), propylene glycol (PG) and propylene carbonate (PC) very effectively using KI, an abundant and cheap salt, as the catalyst. The main reasons are that glycerol and PG are not only the reactant and product, respectively, but also act as the effective co-catalysts to promote the key step of the coupled reaction, and the reaction is thermodynamically favorable. This effective and atom economic route to convert glycerol and CO2 simultaneously has great potential application.
语种	英语
出版者	ROYAL SOC CHEMISTRY
WOS记录号	WOS:000304558500027
内容类型	期刊论文
源URL	[http://ir.iccas.ac.cn/handle/121111/48623]
专题	中国科学院化学研究所
通讯作者	Ma, Jun
作者单位	Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, Beijing 100080, Peoples R China
推荐引用方式 GB/T 7714	Ma, Jun,Song, Jinliang,Liu, Huizhen,et al. One-pot conversion of CO2 and glycerol to value-added products using propylene oxide as the coupling agent[J]. GREEN CHEMISTRY,2012,14(6):1743-1748.
APA	Ma, Jun.,Song, Jinliang.,Liu, Huizhen.,Liu, Jinli.,Zhang, Zhaofu.,...&Han, Buxing.(2012).One-pot conversion of CO2 and glycerol to value-added products using propylene oxide as the coupling agent.GREEN CHEMISTRY,14(6),1743-1748.
MLA	Ma, Jun,et al."One-pot conversion of CO2 and glycerol to value-added products using propylene oxide as the coupling agent".GREEN CHEMISTRY 14.6(2012):1743-1748.