Mechanical alloying preparation of fullerene-like Co3C nanoparticles with high hydrogen storage ability | |
Gao, Peng1; Wang, Ying1; Yang, Shaoqiang1; Chen, Yujin2; Xue, Zhu1; Wang, Longqiang1; Li, Guobao3,4; Sun, Yuzeng3,4 | |
刊名 | INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
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2012-11-01 | |
卷号 | 37期号:22页码:17126-17130 |
关键词 | Co3c Fullerene Nanoparticle Ball-milling Hydrogen Storage |
ISSN号 | 0360-3199 |
DOI | 10.1016/j.ijhydene.2012.07.133 |
英文摘要 | Fullerene-like orthorhombic-structured Co3C nanoparticles have been synthesized by direct ball-milling of Co and graphene (GE) powders with different Co/GE weight ratios. Electrochemical measurements showed that the Co3C nanoparticles displayed excellent electrochemical hydrogen storage capacities and the maximum capacity reached 1415 mA h/g (5.176 wt% hydrogen) at room temperature and ambient pressure. The reaction mechanism and the reasons for the differences of the Co3C electrodes were also investigated. It was found that the quasi-reversible Co3CHx/Co3C reaction was dominant for all the Co3C electrodes. Copyright (C) 2012, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved. |
语种 | 英语 |
出版者 | PERGAMON-ELSEVIER SCIENCE LTD |
WOS记录号 | WOS:000311188500042 |
内容类型 | 期刊论文 |
源URL | [http://ir.iccas.ac.cn/handle/121111/48601] ![]() |
专题 | 中国科学院化学研究所 |
通讯作者 | Gao, Peng |
作者单位 | 1.Harbin Engn Univ, Key Lab Superlight Mat & Surface Technol, Minist Educ, Harbin 150001, Heilongjiang, Peoples R China 2.Harbin Engn Univ, Coll Sci, Harbin 150001, Peoples R China 3.Peking Univ, Beijing Natl Lab Mol Sci, Coll Chem & Mol Engn, Beijing 100871, Peoples R China 4.Peking Univ, State Key Lab Rare Earth Mat Chem & Applicat, Coll Chem & Mol Engn, Beijing 100871, Peoples R China |
推荐引用方式 GB/T 7714 | Gao, Peng,Wang, Ying,Yang, Shaoqiang,et al. Mechanical alloying preparation of fullerene-like Co3C nanoparticles with high hydrogen storage ability[J]. INTERNATIONAL JOURNAL OF HYDROGEN ENERGY,2012,37(22):17126-17130. |
APA | Gao, Peng.,Wang, Ying.,Yang, Shaoqiang.,Chen, Yujin.,Xue, Zhu.,...&Sun, Yuzeng.(2012).Mechanical alloying preparation of fullerene-like Co3C nanoparticles with high hydrogen storage ability.INTERNATIONAL JOURNAL OF HYDROGEN ENERGY,37(22),17126-17130. |
MLA | Gao, Peng,et al."Mechanical alloying preparation of fullerene-like Co3C nanoparticles with high hydrogen storage ability".INTERNATIONAL JOURNAL OF HYDROGEN ENERGY 37.22(2012):17126-17130. |
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