Rh(II)-catalyzed [2,3]-sigmatropic rearrangement of sulfur ylides derived from N-tosylhydrazones and sulfides

doi:10.1016/j.tet.2012.03.032

CORC > 化学研究所 > 中国科学院化学研究所

	Rh(II)-catalyzed [2,3]-sigmatropic rearrangement of sulfur ylides derived from N-tosylhydrazones and sulfides
	Li, Yuye 1,2,3; Huang, Zhongxing 2,3; Wu, Xinhu 1,2,3; Xu, Peng-Fei 1; Jin, Jing 1; Zhang, Yan 1,2,3; Wang, Jianbo 2,3
刊名	TETRAHEDRON
	2012-07-01
卷号	68 期号:26 页码:5234-5240
关键词	Sulfur Ylides N-tosylhydrazone Allylic Phenyl Sulfides Propargyl Phenyl Sulfides [2 3]-sigmatropic Rearrangement
ISSN号	0040-4020
DOI	10.1016/j.tet.2012.03.032
英文摘要	In this paper, Rh-2(OAc)(4)-catalyzed [2,3]-sigmatropic rearrangement of sulfur ylides derived from N-tosylhydrazones and sulfides is reported. A series of tosylhydrazones derived from aldehydes were successfully used for [2,3]-sigmatropic rearrangement by reaction with either allylic phenyl sulfides or propargyl phenyl sulfides. The reaction conditions were optimized and afforded the products in moderate to good yields. In addition, a novel and convenient approach for the synthesis of cyclobutenones and cyclopropanes has been developed through direct oxidation of the rearrangement products. (C) 2012 Elsevier Ltd. All rights reserved.
语种	英语
出版者	PERGAMON-ELSEVIER SCIENCE LTD
WOS记录号	WOS:000305381700019
内容类型	期刊论文
源URL	[http://ir.iccas.ac.cn/handle/121111/48213]
专题	中国科学院化学研究所
通讯作者	Xu, Peng-Fei
作者单位	1.Lanzhou Univ, State Key Lab Appl Organ Chem, Lanzhou 730000, Peoples R China 2.Peking Univ, BNLMS, Coll Chem, Minist Educ, Beijing 100871, Peoples R China 3.Peking Univ, Key Lab Bioorgan Chem & Mol Engn, Coll Chem, Minist Educ, Beijing 100871, Peoples R China
推荐引用方式 GB/T 7714	Li, Yuye,Huang, Zhongxing,Wu, Xinhu,et al. Rh(II)-catalyzed [2,3]-sigmatropic rearrangement of sulfur ylides derived from N-tosylhydrazones and sulfides[J]. TETRAHEDRON,2012,68(26):5234-5240.
APA	Li, Yuye.,Huang, Zhongxing.,Wu, Xinhu.,Xu, Peng-Fei.,Jin, Jing.,...&Wang, Jianbo.(2012).Rh(II)-catalyzed [2,3]-sigmatropic rearrangement of sulfur ylides derived from N-tosylhydrazones and sulfides.TETRAHEDRON,68(26),5234-5240.
MLA	Li, Yuye,et al."Rh(II)-catalyzed [2,3]-sigmatropic rearrangement of sulfur ylides derived from N-tosylhydrazones and sulfides".TETRAHEDRON 68.26(2012):5234-5240.