Trimetallic yttrium N-(2-methylquinolin-8-yl)benzamides: synthesis, structure and use in ring-opening polymerization (ROP) of epsilon-caprolactone

doi:10.1039/c2nj40711f

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	Trimetallic yttrium N-(2-methylquinolin-8-yl)benzamides: synthesis, structure and use in ring-opening polymerization (ROP) of epsilon-caprolactone
	Zhang, Wenjuan 1,2; Liu, Shaofeng 1,2; Sun, Wen-Hua1,2,3 ; Hao, Xiang 1,2; Redshaw, Carl 4
刊名	NEW JOURNAL OF CHEMISTRY
	2012-11-01
卷号	36 期号:11 页码:2392-2396
ISSN号	1144-0546
DOI	10.1039/c2nj40711f
英文摘要	A series of trimetallic yttrium complexes, L7Y3Cl2 [L = N-(2-methylquinolin-8-yl)-p-R-benzamides, 1: R = H; 2: R = OMe; 3: R = Me; 4: R = Cl], has been synthesized by the stoichiometric reaction of YCl3(THF)(2) with the corresponding potassium amidates. All complexes have been characterized by elemental analysis and NMR spectroscopy. The molecular structure of complex 1 bearing seven amidate ligands was confirmed by single-crystal X-ray diffraction. Screening of these complexes, in the presence of BnOH, for ring-opening polymerization of caprolactone (epsilon-CL) revealed effective activities.
语种	英语
出版者	ROYAL SOC CHEMISTRY
WOS记录号	WOS:000310721000036
内容类型	期刊论文
源URL	[http://ir.iccas.ac.cn/handle/121111/47757]
专题	中国科学院化学研究所
通讯作者	Sun, Wen-Hua
作者单位	1.Chinese Acad Sci, Key Lab Engn Plast, Inst Chem, Beijing 100190, Peoples R China 2.Chinese Acad Sci, Beijing Natl Lab Mol Sci, Inst Chem, Beijing 100190, Peoples R China 3.Chinese Acad Sci, State Key Lab Oxo Synth & Select Oxidat, Lanzhou Inst Chem Phys, Lanzhou 730000, Peoples R China 4.Univ E Anglia, Sch Chem, Norwich NR4 7TJ, Norfolk, England
推荐引用方式 GB/T 7714	Zhang, Wenjuan,Liu, Shaofeng,Sun, Wen-Hua,et al. Trimetallic yttrium N-(2-methylquinolin-8-yl)benzamides: synthesis, structure and use in ring-opening polymerization (ROP) of epsilon-caprolactone[J]. NEW JOURNAL OF CHEMISTRY,2012,36(11):2392-2396.
APA	Zhang, Wenjuan,Liu, Shaofeng,Sun, Wen-Hua,Hao, Xiang,&Redshaw, Carl.(2012).Trimetallic yttrium N-(2-methylquinolin-8-yl)benzamides: synthesis, structure and use in ring-opening polymerization (ROP) of epsilon-caprolactone.NEW JOURNAL OF CHEMISTRY,36(11),2392-2396.
MLA	Zhang, Wenjuan,et al."Trimetallic yttrium N-(2-methylquinolin-8-yl)benzamides: synthesis, structure and use in ring-opening polymerization (ROP) of epsilon-caprolactone".NEW JOURNAL OF CHEMISTRY 36.11(2012):2392-2396.