Seven-Coordinate Lanthanide Sandwich-Type Complexes with a Tetrathiafulvalene-Fused Schiff Base Ligand

doi:10.1021/ic401421h

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	Seven-Coordinate Lanthanide Sandwich-Type Complexes with a Tetrathiafulvalene-Fused Schiff Base Ligand
	Gao, Feng 1; Cui, Long 1; Liu, Wei 2; Hu, Liang 1; Zhong, Yu-Wu 3; Li, Yi-Zhi 1; Zuo, Jing-Lin 1
刊名	INORGANIC CHEMISTRY
	2013-10-07
卷号	52 期号:19 页码:11164-11172
ISSN号	0020-1669
DOI	10.1021/ic401421h
英文摘要	Three seven-coordinate lanthanide(III) sandwich-type mononuclear complexes with pi-conjugated TTF-Schiff base ligand H2L (L2- = 2,2'-((2-(4,5-bis(methylthio)-1,3-dithiol-2-ylidene)-1,3-benzodithiole-5,6-diyl)bis(nitrilomethylidyne)bis(4-chlorophenolate)) and the tripodal ligand L-OEt(-) (L-OEt(-) = [eta(5)-C5H5)Co(P(=O)(OEt)(2))(3)](-)), [(L-OEt)Ln(L)]center dot 0.25H(2)O (Ln(3+) = Dy3+, 1; Tb3+, 2; Ho3+, 3), have been synthesized and structurally characterized. All of the complexes are also characterized by absorption spectra and electrochemical, spectroelectrochemical, and magnetic studies. The Dy complex exhibits the field-induced slow relaxation of magnetization with an energy barrier of 41.6 K, indicating it shows single lanthanide-based SMM behavior. Introduction of the redox-active TTF unit into the sandwich-type lanthanide(III) complexes with interesting magnetic properties renders them promising for elaboration of new hybrid inorganic-organic materials.
语种	英语
出版者	AMER CHEMICAL SOC
WOS记录号	WOS:000326319800059
内容类型	期刊论文
源URL	[http://ir.iccas.ac.cn/handle/121111/47097]
专题	中国科学院化学研究所
通讯作者	Zuo, Jing-Lin
作者单位	1.Nanjing Univ, Sch Chem & Chem Engn, State Key Lab Coordinat Chem, Nanjing Natl Lab Microstruct, Nanjing 210093, Jiangsu, Peoples R China 2.Soochow Univ, Coll Chem Chem Engn & Mat Sci, Suzhou 215006, Peoples R China 3.Chinese Acad Sci, Beijing Natl Lab Mol Sci, Inst Chem, Beijing 100190, Peoples R China
推荐引用方式 GB/T 7714	Gao, Feng,Cui, Long,Liu, Wei,et al. Seven-Coordinate Lanthanide Sandwich-Type Complexes with a Tetrathiafulvalene-Fused Schiff Base Ligand[J]. INORGANIC CHEMISTRY,2013,52(19):11164-11172.
APA	Gao, Feng.,Cui, Long.,Liu, Wei.,Hu, Liang.,Zhong, Yu-Wu.,...&Zuo, Jing-Lin.(2013).Seven-Coordinate Lanthanide Sandwich-Type Complexes with a Tetrathiafulvalene-Fused Schiff Base Ligand.INORGANIC CHEMISTRY,52(19),11164-11172.
MLA	Gao, Feng,et al."Seven-Coordinate Lanthanide Sandwich-Type Complexes with a Tetrathiafulvalene-Fused Schiff Base Ligand".INORGANIC CHEMISTRY 52.19(2013):11164-11172.