Synergistic Effect between a Novel Char Forming Agent and Ammonium Polyphosphate on Flame Retardancy and Thermal Properties of Polypropylene

doi:10.1021/ie401058u

CORC > 化学研究所 > 中国科学院化学研究所

	Synergistic Effect between a Novel Char Forming Agent and Ammonium Polyphosphate on Flame Retardancy and Thermal Properties of Polypropylene
	Tian, Nana 1; Wen, Xin 1; Jiang, Zhiwei 1,2; Gong, Jiang 1,2; Wang, Yanhui 1; Xue, Jian 1; Tang, Tao 1
刊名	INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
	2013-08-14
卷号	52 期号:32 页码:10905-10915
ISSN号	0888-5885
DOI	10.1021/ie401058u
英文摘要	The performances of a novel char forming agent containing spiro and caged bicyclic phosphate (SBCPO) and its mixture with ammonium polyphosphate (APP) were investigated. The flame retardancy of the polypropylene (PP)/SBCPO/APP system was evaluated by the limiting oxygen index (LOI), the UL-94 test, and the cone calorimeter test. The maximum LOI value of PP/intumescent flame retardant (IFR) could reach 30.5 and passed the UL-94 V-0 rating. An obvious synergistic effect could be observed between SBCPO and APP by TGA. DSC, and synergistic effectivity studies, which remarkably improved the flame retardant properties of PP. FTIR analysis indicated that APP could accelerate the decomposition of SBCPO due to the interaction between them. The thermal degradation kinetics results of the PP/IFR system by the Kissinger method and the Flynn-Wall-Ozawa method showed that the apparent activation energy (E-a) increased with the increase of content for flame retardants.
语种	英语
出版者	AMER CHEMICAL SOC
WOS记录号	WOS:000323240900005
内容类型	期刊论文
源URL	[http://ir.iccas.ac.cn/handle/121111/46971]
专题	中国科学院化学研究所
通讯作者	Tang, Tao
作者单位	1.Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100039, Peoples R China
推荐引用方式 GB/T 7714	Tian, Nana,Wen, Xin,Jiang, Zhiwei,et al. Synergistic Effect between a Novel Char Forming Agent and Ammonium Polyphosphate on Flame Retardancy and Thermal Properties of Polypropylene[J]. INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH,2013,52(32):10905-10915.
APA	Tian, Nana.,Wen, Xin.,Jiang, Zhiwei.,Gong, Jiang.,Wang, Yanhui.,...&Tang, Tao.(2013).Synergistic Effect between a Novel Char Forming Agent and Ammonium Polyphosphate on Flame Retardancy and Thermal Properties of Polypropylene.INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH,52(32),10905-10915.
MLA	Tian, Nana,et al."Synergistic Effect between a Novel Char Forming Agent and Ammonium Polyphosphate on Flame Retardancy and Thermal Properties of Polypropylene".INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH 52.32(2013):10905-10915.