Self-assembly of linear rod-coil multiblock copolymers

doi:10.1007/s10118-013-1322-8

CORC > 化学研究所 > 中国科学院化学研究所

	Self-assembly of linear rod-coil multiblock copolymers
	Xia, Ying-dong; Chen, Ji-zhong; Shi, Tong-fei; An, Li-jia
刊名	CHINESE JOURNAL OF POLYMER SCIENCE
	2013-09-01
卷号	31 期号:9 页码:1242-1249
关键词	Rod-coil Multiblock Copolymer Self-assembly Self-consistent-field Lattice
ISSN号	0256-7679
DOI	10.1007/s10118-013-1322-8
英文摘要	The self-assembly of the linear rod-coil multiblock copolymers is studied by applying self-consistent-field lattice techniques in a three-dimensional (3D) space. Compared to the copolymer with one rod, the copolymer with more rods (m (rod) a parts per thousand yen 2) exhibits rich order-order phase transitions with increasing temperature, where the ordered morphology changes from strips to perforated lamellae and finally to lamellae. In addition, taking the copolymer with m (rod) = 2 as a representative, we further study the effects of the volume fractions of the rods, the spacer coils and the end coils on the phase behaviors respectively, by which the detailed self-assembled mechanism of the linear rod-coil multiblock copolymers is revealed. Our results are expected to provide guidance for the design of the rod-coil materials.
语种	英语
出版者	SPRINGER
WOS记录号	WOS:000322453700007
内容类型	期刊论文
源URL	[http://ir.iccas.ac.cn/handle/121111/46745]
专题	中国科学院化学研究所
通讯作者	Chen, Ji-zhong
作者单位	Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China
推荐引用方式 GB/T 7714	Xia, Ying-dong,Chen, Ji-zhong,Shi, Tong-fei,et al. Self-assembly of linear rod-coil multiblock copolymers[J]. CHINESE JOURNAL OF POLYMER SCIENCE,2013,31(9):1242-1249.
APA	Xia, Ying-dong,Chen, Ji-zhong,Shi, Tong-fei,&An, Li-jia.(2013).Self-assembly of linear rod-coil multiblock copolymers.CHINESE JOURNAL OF POLYMER SCIENCE,31(9),1242-1249.
MLA	Xia, Ying-dong,et al."Self-assembly of linear rod-coil multiblock copolymers".CHINESE JOURNAL OF POLYMER SCIENCE 31.9(2013):1242-1249.