Integrating TEMPO and Its Analogues with Visible-Light Photocatalysis

doi:10.1002/asia.201701765

CORC > 化学研究所 > 中国科学院化学研究所

	Integrating TEMPO and Its Analogues with Visible-Light Photocatalysis
	Lang, Xianjun 1; Zhao, Jincai 2
刊名	CHEMISTRY-AN ASIAN JOURNAL
	2018-03-16
卷号	13 期号:6 页码:599-613
关键词	Oxidation Photocatalysis Radicals Synthesis Design Visible Light
ISSN号	1861-4728
DOI	10.1002/asia.201701765
英文摘要	Visible light has risen to become a very important facilitator for selective radical reactions enabled by well-cognized photocatalysts. The renaissance of visible-light photocatalysis on this matter partly relies on integrating it with other fields of catalysis. In parallel, 2,2,6,6-tetramethylpiperidin N-oxide (TEMPO), a quintessential persistent radical, has a wide range of uses owing to its exceptional redox behavior, which gives rise to its latest prominence in catalysis. Therefore, integrating the catalysis of TEMPO with photocatalysis to perform visible-light-induced selective reactions becomes a very convenient marriage of merits. In this context, the integration of different types of photocatalysts, including metal complexes, metal-free organic dyes, and semiconductors, with TEMPO for outstanding organic transformations will be summarized. To expand further the catalytic repertoire, the integration of TEMPOH analogues such as NHPI (N-hydroxyphthalimide) and NHS (N-hydroxysuccinimide) with photocatalysis will also be discussed. Hopefully, these advances will pave the way for more breakthroughs by integrating TEMPO and its analogues with photocatalysis to lead to a valuable blueprint for visible-light-induced selective organic transformations.
语种	英语
出版者	WILEY-V C H VERLAG GMBH
WOS记录号	WOS:000428378000002
内容类型	期刊论文
源URL	[http://ir.iccas.ac.cn/handle/121111/46251]
专题	中国科学院化学研究所
通讯作者	Lang, Xianjun
作者单位	1.Wuhan Univ, Coll Chem & Mol Sci, Wuhan 430072, Hubei, Peoples R China 2.Chinese Acad Sci, Key Lab Photochem, Inst Chem, Beijing 100190, Peoples R China
推荐引用方式 GB/T 7714	Lang, Xianjun,Zhao, Jincai. Integrating TEMPO and Its Analogues with Visible-Light Photocatalysis[J]. CHEMISTRY-AN ASIAN JOURNAL,2018,13(6):599-613.
APA	Lang, Xianjun,&Zhao, Jincai.(2018).Integrating TEMPO and Its Analogues with Visible-Light Photocatalysis.CHEMISTRY-AN ASIAN JOURNAL,13(6),599-613.
MLA	Lang, Xianjun,et al."Integrating TEMPO and Its Analogues with Visible-Light Photocatalysis".CHEMISTRY-AN ASIAN JOURNAL 13.6(2018):599-613.