B(C6F5)(3)-catalyzed metal-free hydrogenations of 2-quinolinecarboxylates

doi:10.1016/j.tetlet.2018.02.057

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	B(C6F5)(3)-catalyzed metal-free hydrogenations of 2-quinolinecarboxylates
	Han, Caifang 1,2; Zhang, E.3; Feng, Xiangqing 1,4; Wang, Shoufeng 3; Du, Haifeng 1,4
刊名	TETRAHEDRON LETTERS
	2018-04-04
卷号	59 期号:14 页码:1400-1403
关键词	2-quinolinecarboxylates Metal-free Hydrogenation Tetrahydroquinolines Frustrated Lewis Pairs
ISSN号	0040-4039
DOI	10.1016/j.tetlet.2018.02.057
英文摘要	A metal-free hydrogenation of 2-quinolinecarboxylates has been realized by using 5 mol% of B(C6F5)(3) as catalyst. A variety of tetrahydroquinolines were obtained in 57-99% yields. An attempt for the asymmetric hydrogenation with chiral boron Lewis acids generated from chiral dienes afforded very low ee's. (C) 2018 Elsevier Ltd. All rights reserved.
语种	英语
出版者	PERGAMON-ELSEVIER SCIENCE LTD
WOS记录号	WOS:000429513800024
内容类型	期刊论文
源URL	[http://ir.iccas.ac.cn/handle/121111/46215]
专题	中国科学院化学研究所
通讯作者	Feng, Xiangqing; Wang, Shoufeng; Du, Haifeng
作者单位	1.Chinese Acad Sci, Beijing Natl Lab Mol Sci, Inst Chem, CAS Key Lab Mol Recognit & Funct, Beijing 100190, Peoples R China 2.Hebei Normal Univ, Coll Chem & Mat Sci, Shijiazhuang 050024, Hebei, Peoples R China 3.Univ Jinan, Coll Chem & Chem Engn, Shandong Prov Key Lab Fluorine Chem & Chem Mat, Jinan 250022, Shandong, Peoples R China 4.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
推荐引用方式 GB/T 7714	Han, Caifang,Zhang, E.,Feng, Xiangqing,et al. B(C6F5)(3)-catalyzed metal-free hydrogenations of 2-quinolinecarboxylates[J]. TETRAHEDRON LETTERS,2018,59(14):1400-1403.
APA	Han, Caifang,Zhang, E.,Feng, Xiangqing,Wang, Shoufeng,&Du, Haifeng.(2018).B(C6F5)(3)-catalyzed metal-free hydrogenations of 2-quinolinecarboxylates.TETRAHEDRON LETTERS,59(14),1400-1403.
MLA	Han, Caifang,et al."B(C6F5)(3)-catalyzed metal-free hydrogenations of 2-quinolinecarboxylates".TETRAHEDRON LETTERS 59.14(2018):1400-1403.