Design and Application of a High-Temperature Linear Ion Trap Reactor

doi:10.1007/s13361-017-1828-3

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	Design and Application of a High-Temperature Linear Ion Trap Reactor
	Jiang, Li-Xue 1,2; Liu, Qing-Yu 1,2; Li, Xiao-Na 1; He, Sheng-Gui 1,2
刊名	JOURNAL OF THE AMERICAN SOCIETY FOR MASS SPECTROMETRY
	2018
卷号	29 期号:1 页码:78-84
关键词	Ion-molecule Reactions Mass Spectrometry Ion Trap Co Oxidation Variable Temperature Density Functional Theory
ISSN号	1044-0305
DOI	10.1007/s13361-017-1828-3
英文摘要	A high-temperature linear ion trap reactor with hexapole design was homemade to study ion-molecule reactions at variable temperatures. The highest temperature for the trapped ions is up to 773 K, which is much higher than those in available reports. The reaction between V2O6 (-) cluster anions and CO at different temperatures was investigated to evaluate the performance of this reactor. The apparent activation energy was determined to be 0.10 +/- 0.02 eV, which is consistent with the barrier of 0.12 eV calculated by density functional theory. This indicates that the current experimental apparatus is prospective to study ion-molecule reactions at variable temperatures, and more kinetic details can be obtained to have a better understanding of chemical reactions that have overall barriers.
语种	英语
出版者	SPRINGER
WOS记录号	WOS:000423390800010
内容类型	期刊论文
源URL	[http://ir.iccas.ac.cn/handle/121111/45483]
专题	中国科学院化学研究所
通讯作者	Li, Xiao-Na; He, Sheng-Gui
作者单位	1.Chinese Acad Sci, Beijing Natl Lab Mol Sci, State Key Lab Struct Chem Unstable & Stable Speci, CAS Res Educ Ctr Excellence Mol Sci,Inst Chem, Beijing 100190, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
推荐引用方式 GB/T 7714	Jiang, Li-Xue,Liu, Qing-Yu,Li, Xiao-Na,et al. Design and Application of a High-Temperature Linear Ion Trap Reactor[J]. JOURNAL OF THE AMERICAN SOCIETY FOR MASS SPECTROMETRY,2018,29(1):78-84.
APA	Jiang, Li-Xue,Liu, Qing-Yu,Li, Xiao-Na,&He, Sheng-Gui.(2018).Design and Application of a High-Temperature Linear Ion Trap Reactor.JOURNAL OF THE AMERICAN SOCIETY FOR MASS SPECTROMETRY,29(1),78-84.
MLA	Jiang, Li-Xue,et al."Design and Application of a High-Temperature Linear Ion Trap Reactor".JOURNAL OF THE AMERICAN SOCIETY FOR MASS SPECTROMETRY 29.1(2018):78-84.