Synthesis of Metal Complexes with an Open-Cage Fullerene as the Ligand

doi:10.1002/chem.201704517

CORC > 化学研究所 > 中国科学院化学研究所

	Synthesis of Metal Complexes with an Open-Cage Fullerene as the Ligand
	Zhou, Zishuo 1; Xin, Nana 1; Gan, Liangbing 1,2
刊名	CHEMISTRY-A EUROPEAN JOURNAL
	2018-01-09
卷号	24 期号:2 页码:451-457
关键词	Fullerene Ligand Metal Complex Open-cage Peroxide
ISSN号	0947-6539
DOI	10.1002/chem.201704517
英文摘要	An open-cage C-60 derivative 9 with anilino, hemiketal, and lactone moieties on the edge of the opening was prepared through a fullerene-mixed peroxide procedure. Key steps include decarbonylation, intramolecular Friedel-Crafts reaction and oxetane ring opening rearrangement. The open-cage compound9 readily reacts with various metal salts. A nickel complex was obtained by treating 9 with NiCl2 at r.t. followed by purification on a silica gel column. Single-crystal X-ray diffraction analysis showed that the nickel ion is coordinated to two ligands with an octahedral geometry.
语种	英语
出版者	WILEY-V C H VERLAG GMBH
WOS记录号	WOS:000419623600025
内容类型	期刊论文
源URL	[http://ir.iccas.ac.cn/handle/121111/45373]
专题	中国科学院化学研究所
通讯作者	Gan, Liangbing
作者单位	1.Peking Univ, Beijing Natl Lab Mol Sci, Coll Chem & Mol Engn, Minist Educ,Key Lab Bioorgan Chem & Mol Engn, Beijing 100871, Peoples R China 2.Shanghai Inst Organ Chem, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China
推荐引用方式 GB/T 7714	Zhou, Zishuo,Xin, Nana,Gan, Liangbing. Synthesis of Metal Complexes with an Open-Cage Fullerene as the Ligand[J]. CHEMISTRY-A EUROPEAN JOURNAL,2018,24(2):451-457.
APA	Zhou, Zishuo,Xin, Nana,&Gan, Liangbing.(2018).Synthesis of Metal Complexes with an Open-Cage Fullerene as the Ligand.CHEMISTRY-A EUROPEAN JOURNAL,24(2),451-457.
MLA	Zhou, Zishuo,et al."Synthesis of Metal Complexes with an Open-Cage Fullerene as the Ligand".CHEMISTRY-A EUROPEAN JOURNAL 24.2(2018):451-457.