Rhodium(II)- or Copper(I)-Catalyzed Formal Intramolecular Carbene Insertion into Vinylic C(sp(2))-H Bonds: Access to Substituted 1H-Indenes

doi:10.1002/anie.201709375

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	Rhodium(II)- or Copper(I)-Catalyzed Formal Intramolecular Carbene Insertion into Vinylic C(sp(2))-H Bonds: Access to Substituted 1H-Indenes
	Zhou, Qi 1,2; Li, Shichao 1,2; Zhang, Yan 1,2; Wang, Jianbo 1,2,3
刊名	ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
	2017-12-11
卷号	56 期号:50 页码:16013-16017
关键词	Diazo Compounds Indenes Insertion Metal Carbenes N-tosylhydrazones
ISSN号	1433-7851
DOI	10.1002/anie.201709375
英文摘要	A rhodium(II)- or copper(I)-catalyzed formal intramolecular carbene insertion into vinylic C(sp(2))-H bonds is reported herein. This method provides straightforward access to 1H-indenes with high efficiency and excellent functional-group compatibility. Mechanistically, the reaction is proposed to involve the following sequence: metal carbene formation, intramolecular nucleophilic addition of the double bond to the electron-deficient carbene carbon atom, dearomatization, and finally a 1,5-H shift.
语种	英语
出版者	WILEY-V C H VERLAG GMBH
WOS记录号	WOS:000417200600039
内容类型	期刊论文
源URL	[http://ir.iccas.ac.cn/handle/121111/45301]
专题	中国科学院化学研究所
通讯作者	Wang, Jianbo
作者单位	1.Peking Univ, Coll Chem, BNLMS, Beijing 100871, Peoples R China 2.Peking Univ, Coll Chem, Minist Educ, Key Lab Bioorgan Chem & Mol Engn, Beijing 100871, Peoples R China 3.Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China
推荐引用方式 GB/T 7714	Zhou, Qi,Li, Shichao,Zhang, Yan,et al. Rhodium(II)- or Copper(I)-Catalyzed Formal Intramolecular Carbene Insertion into Vinylic C(sp(2))-H Bonds: Access to Substituted 1H-Indenes[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2017,56(50):16013-16017.
APA	Zhou, Qi,Li, Shichao,Zhang, Yan,&Wang, Jianbo.(2017).Rhodium(II)- or Copper(I)-Catalyzed Formal Intramolecular Carbene Insertion into Vinylic C(sp(2))-H Bonds: Access to Substituted 1H-Indenes.ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,56(50),16013-16017.
MLA	Zhou, Qi,et al."Rhodium(II)- or Copper(I)-Catalyzed Formal Intramolecular Carbene Insertion into Vinylic C(sp(2))-H Bonds: Access to Substituted 1H-Indenes".ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 56.50(2017):16013-16017.