A mechanistic study on the electrochemical reduction of beta-naphthyl sulfonic acid in acetonitrile solution at mercury electrode | |
Huang, SK; Chen, DW; Huang, SH | |
刊名 | ACTA CHIMICA SINICA
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1996 | |
卷号 | 54期号:8页码:783-789 |
ISSN号 | 0567-7351 |
英文摘要 | The mechanism of electroreduction of beta-naphthyl sulfonic acid at mercury electrode has been studied by means of cyclic voltammetry, electrochemical-ESR spectroscopy in-situ and SCFMO method (CNDO/2). The results showed that its electroreduction obeys ECE scheme involving the detachment of sulfonic acid group and the formation of beta-naphthyl radical. Some explanation for the electroreduction process has been put forward using molecular orbital theory. |
语种 | 英语 |
出版者 | ACTA CHIMICA SINICA |
WOS记录号 | WOS:A1996VH00600009 |
内容类型 | 期刊论文 |
源URL | [http://ir.iccas.ac.cn/handle/121111/44531] ![]() |
专题 | 中国科学院化学研究所 |
通讯作者 | Huang, SK |
作者单位 | 1.CHINESE ACAD SCI,INST CHEM,BEIJING 100080,PEOPLES R CHINA 2.TSING HUA UNIV,DEPT CHEM ENGN,BEIJING 100084,PEOPLES R CHINA |
推荐引用方式 GB/T 7714 | Huang, SK,Chen, DW,Huang, SH. A mechanistic study on the electrochemical reduction of beta-naphthyl sulfonic acid in acetonitrile solution at mercury electrode[J]. ACTA CHIMICA SINICA,1996,54(8):783-789. |
APA | Huang, SK,Chen, DW,&Huang, SH.(1996).A mechanistic study on the electrochemical reduction of beta-naphthyl sulfonic acid in acetonitrile solution at mercury electrode.ACTA CHIMICA SINICA,54(8),783-789. |
MLA | Huang, SK,et al."A mechanistic study on the electrochemical reduction of beta-naphthyl sulfonic acid in acetonitrile solution at mercury electrode".ACTA CHIMICA SINICA 54.8(1996):783-789. |
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