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A mechanistic study on the electrochemical reduction of beta-naphthyl sulfonic acid in acetonitrile solution at mercury electrode
Huang, SK; Chen, DW; Huang, SH
刊名ACTA CHIMICA SINICA
1996
卷号54期号:8页码:783-789
ISSN号0567-7351
英文摘要The mechanism of electroreduction of beta-naphthyl sulfonic acid at mercury electrode has been studied by means of cyclic voltammetry, electrochemical-ESR spectroscopy in-situ and SCFMO method (CNDO/2). The results showed that its electroreduction obeys ECE scheme involving the detachment of sulfonic acid group and the formation of beta-naphthyl radical. Some explanation for the electroreduction process has been put forward using molecular orbital theory.
语种英语
出版者ACTA CHIMICA SINICA
WOS记录号WOS:A1996VH00600009
内容类型期刊论文
源URL[http://ir.iccas.ac.cn/handle/121111/44531]  
专题中国科学院化学研究所
通讯作者Huang, SK
作者单位1.CHINESE ACAD SCI,INST CHEM,BEIJING 100080,PEOPLES R CHINA
2.TSING HUA UNIV,DEPT CHEM ENGN,BEIJING 100084,PEOPLES R CHINA
推荐引用方式
GB/T 7714
Huang, SK,Chen, DW,Huang, SH. A mechanistic study on the electrochemical reduction of beta-naphthyl sulfonic acid in acetonitrile solution at mercury electrode[J]. ACTA CHIMICA SINICA,1996,54(8):783-789.
APA Huang, SK,Chen, DW,&Huang, SH.(1996).A mechanistic study on the electrochemical reduction of beta-naphthyl sulfonic acid in acetonitrile solution at mercury electrode.ACTA CHIMICA SINICA,54(8),783-789.
MLA Huang, SK,et al."A mechanistic study on the electrochemical reduction of beta-naphthyl sulfonic acid in acetonitrile solution at mercury electrode".ACTA CHIMICA SINICA 54.8(1996):783-789.
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