CALORIMETRIC TITRATION FOR COORDINATION REACTIONS OF DIBENZO-30-CROWN-10 WITH RARE-EARTH PERCHLORATES IN TITRATE OF ACETONITRILE CONTAINING 0.5 VOL PERCENT WATER

CORC > 化学研究所 > 中国科学院化学研究所

	CALORIMETRIC TITRATION FOR COORDINATION REACTIONS OF DIBENZO-30-CROWN-10 WITH RARE-EARTH PERCHLORATES IN TITRATE OF ACETONITRILE CONTAINING 0.5 VOL PERCENT WATER
	LIU, HG ; LIU, DQ ; ZHANG, JH ; JIANG, BG ; YAN, HK
刊名	THERMOCHIMICA ACTA
	1992-06-19
卷号	202 页码:223-232
ISSN号	0040-6031
英文摘要	The coordination reactions of RE(ClO4)3 (RE = La, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Tm, Yb or Lu) with dibenzo-30-crown-10 (DB30C10) acetonitrile containing 0.5 vol.% water were investigated at 298.15 K by titration calorimetry. The formation constants and enthalpies of coordination adducts were calculated by using a program developed for use on an IBM computer. Furthermore, the formation free energies and entropies of the coordination adducts were obtained. Thc results show that adducts of 1:1 stoichiometry between each of the above 12 rare earth cations and DB30C10 are formed under the experimental conditions used, and all the formation enthalpies are negative.
语种	英语
出版者	ELSEVIER SCIENCE BV
WOS记录号	WOS:A1992JF17100023
内容类型	期刊论文
源URL	[http://ir.iccas.ac.cn/handle/121111/44013]
专题	中国科学院化学研究所
作者单位	1.SHANDONG UNIV,DEPT CHEM,JINAN 250100,PEOPLES R CHINA 2.CHINESE ACAD SCI,INST CHEM,BEIJING,PEOPLES R CHINA
推荐引用方式 GB/T 7714	LIU, HG,LIU, DQ,ZHANG, JH,et al. CALORIMETRIC TITRATION FOR COORDINATION REACTIONS OF DIBENZO-30-CROWN-10 WITH RARE-EARTH PERCHLORATES IN TITRATE OF ACETONITRILE CONTAINING 0.5 VOL PERCENT WATER[J]. THERMOCHIMICA ACTA,1992,202:223-232.
APA	LIU, HG,LIU, DQ,ZHANG, JH,JIANG, BG,&YAN, HK.(1992).CALORIMETRIC TITRATION FOR COORDINATION REACTIONS OF DIBENZO-30-CROWN-10 WITH RARE-EARTH PERCHLORATES IN TITRATE OF ACETONITRILE CONTAINING 0.5 VOL PERCENT WATER.THERMOCHIMICA ACTA,202,223-232.
MLA	LIU, HG,et al."CALORIMETRIC TITRATION FOR COORDINATION REACTIONS OF DIBENZO-30-CROWN-10 WITH RARE-EARTH PERCHLORATES IN TITRATE OF ACETONITRILE CONTAINING 0.5 VOL PERCENT WATER".THERMOCHIMICA ACTA 202(1992):223-232.