Rhodium-Catalyzed Formylation of Aryl Halides with CO2 and H-2

doi:10.1021/acs.orglett.8b02027

CORC > 化学研究所 > 中国科学院化学研究所

	Rhodium-Catalyzed Formylation of Aryl Halides with CO2 and H-2
	Liu, Zhenghui 1,2; Yang, Zhenzhen 1; Yu, Bo 1; Yu, Xiaoxiao 1,2; Zhang, Hongye 1; Zhao, Yanfei 1; Yang, Peng 1,2; Liu, Zhimin 1,2
刊名	ORGANIC LETTERS
	2018-09-07
卷号	20 期号:17 页码:5130-5134
ISSN号	1523-7060
DOI	10.1021/acs.orglett.8b02027
英文摘要	The reductive formylation of aryl iodides/bromides to aryl aldehydes using CO2/H-2 is presented for the first time. It was realized over a catalytic system composed of RhI3 or RhI3/Pd(dppp)Cl-2 (dppp = 1,3-bis(diphenyphosphino)propane) and PPh3 in the presence of Ac2O/Et3N at 100 degrees C, affording aromatic aldehydes in good to excellent yields, together with good functional-group tolerance and broad substrate scope. The reaction proceeds through three cascade steps, involving HCOOH formation, CO release, and formylation of aryl halides.
语种	英语
出版者	AMER CHEMICAL SOC
WOS记录号	WOS:000444527000013
内容类型	期刊论文
源URL	[http://ir.iccas.ac.cn/handle/121111/43101]
专题	中国科学院化学研究所
通讯作者	Liu, Zhimin
作者单位	1.Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, Key Lab Colloid Interface & Thermodynam, Beijing 100190, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
推荐引用方式 GB/T 7714	Liu, Zhenghui,Yang, Zhenzhen,Yu, Bo,et al. Rhodium-Catalyzed Formylation of Aryl Halides with CO2 and H-2[J]. ORGANIC LETTERS,2018,20(17):5130-5134.
APA	Liu, Zhenghui.,Yang, Zhenzhen.,Yu, Bo.,Yu, Xiaoxiao.,Zhang, Hongye.,...&Liu, Zhimin.(2018).Rhodium-Catalyzed Formylation of Aryl Halides with CO2 and H-2.ORGANIC LETTERS,20(17),5130-5134.
MLA	Liu, Zhenghui,et al."Rhodium-Catalyzed Formylation of Aryl Halides with CO2 and H-2".ORGANIC LETTERS 20.17(2018):5130-5134.