Renewable and Biocompatible Lecithin as an Efficient Organocatalyst for Reductive Conversion of CO2 with Amines to Formamides and Methylamines

doi:10.1021/acssuschemeng.8b03245

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	Renewable and Biocompatible Lecithin as an Efficient Organocatalyst for Reductive Conversion of CO2 with Amines to Formamides and Methylamines
	Hu, Yue 1,2; Song, Jinliang 1; Xie, Chao 1,2; Wu, Haoran 1,2; Wang, Zhenpeng 1; Jiang, Tao 1; Wu, Lei 3; Wang, Yu 3; Han, Buxing 1,2
刊名	ACS SUSTAINABLE CHEMISTRY & ENGINEERING
	2018-09-01
卷号	6 期号:9 页码:11228-11234
关键词	Transformation Of Carbon Dioxide Lecithin C-n Bond Construction Formylation And Methylation Renewable Organocatalyst
ISSN号	2168-0485
DOI	10.1021/acssuschemeng.8b03245
英文摘要	Transformation of carbon dioxide (CO2) into valuable chemicals is of great importance, and development of novel and efficient catalysts is crucial. Herein, we found that the renewable lecithin could be used as an efficient organocatalyst for the formylation and methylation of various amines with CO2 to corresponding formamides and methylamines via the construction of new C-N bonds using PhSiH3 as the hydrogen source, and satisfactory yields could be obtained. More importantly, the selectivity of the products could be easily controlled by the molar ratio of reactants (i.e., CO2, amines, and PhSiH3) and reaction temperature. In the catalytic cycle, formamides and methylamines were generated by converting the carbon (+4) in CO2 into +2 and -2 via 2-electron and 6-electron reduction pathway, respectively.
语种	英语
出版者	AMER CHEMICAL SOC
WOS记录号	WOS:000443924100013
内容类型	期刊论文
源URL	[http://ir.iccas.ac.cn/handle/121111/43083]
专题	中国科学院化学研究所
通讯作者	Song, Jinliang; Jiang, Tao; Han, Buxing
作者单位	1.Chinese Acad Sci, CAS Key Lab Colloid & Interface & Thermodynam, CAS Res Educ Ctr Excellence Mol Sci, Beijing Natl Lab Mol Sci,Inst Chem, Beijing 100190, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 3.Zhejiang NHU Co Co LTD, Xinchang 312500, Peoples R China
推荐引用方式 GB/T 7714	Hu, Yue,Song, Jinliang,Xie, Chao,et al. Renewable and Biocompatible Lecithin as an Efficient Organocatalyst for Reductive Conversion of CO2 with Amines to Formamides and Methylamines[J]. ACS SUSTAINABLE CHEMISTRY & ENGINEERING,2018,6(9):11228-11234.
APA	Hu, Yue.,Song, Jinliang.,Xie, Chao.,Wu, Haoran.,Wang, Zhenpeng.,...&Han, Buxing.(2018).Renewable and Biocompatible Lecithin as an Efficient Organocatalyst for Reductive Conversion of CO2 with Amines to Formamides and Methylamines.ACS SUSTAINABLE CHEMISTRY & ENGINEERING,6(9),11228-11234.
MLA	Hu, Yue,et al."Renewable and Biocompatible Lecithin as an Efficient Organocatalyst for Reductive Conversion of CO2 with Amines to Formamides and Methylamines".ACS SUSTAINABLE CHEMISTRY & ENGINEERING 6.9(2018):11228-11234.