Bio-based phthalonitrile compounds: Synthesis, curing behavior, thermomechanical and thermal properties

doi:10.1016/j.reactfunctpolym.2018.03.017

CORC > 化学研究所 > 中国科学院化学研究所

	Bio-based phthalonitrile compounds: Synthesis, curing behavior, thermomechanical and thermal properties
	Wang, An-ran 1; Dayo, Abdul Qadeer 1; Zu, Li-wu 2; Xu, Yi-le 1; Lv, Dan 1; Song, Sha 1; Tang, Tao 3; Liu, Wen-bin 1; Wang, Jun 1; Gao, Bao-chang 4
刊名	REACTIVE & FUNCTIONAL POLYMERS
	2018-06-01
卷号	127 页码:1-9
关键词	Bio-based Phthalonitrile Curing Behavior Thermomechanical Property Thermal Property
ISSN号	1381-5148
DOI	10.1016/j.reactfunctpolym.2018.03.017
英文摘要	Two bio-based phthalonitrile (PN) monomers, eugenol-based phthalonitrile (EPN) and guaiacol-based phthalonitrile (GPN), were successfully synthesized by the reaction of 4-nitrophthalonitrile with eugenol and guaiacol derived from clove and lignin, respectively, in the presence of potassium carbonate via nucleophilic substitution reaction. Their chemical structures were confirmed by the Fourier transform infrared spectra (FTIR), hydrogen and carbon nuclear magnetic resonances (H-1 and C-13 NMR), and elemental analysis. The curing behavior of the blends of the prepared PN monomers with 10 wt% of 4-(4-aminophenoxy)-phthalonitrile (4-APN) as curing agent was evaluated by FTIR and differential scanning calorimetry (DSC), while rheometer was used to analyze the processability of the blends. Moreover, the thermomechanical and thermal properties of the polymers were studied by dynamic mechanical analyzer (DMA) and thermogravimetric analysis (TGA). The results confirmed that the bio-based PN monomers and its blends show low melting temperatures, wide processing windows (> 186 degrees C), and low melt viscosity (< 0.03 Pa.s). The cured bio-based PN resins exhibited higher glass transition temperature and better thermal stability and toughness than those of typical bisphenol A-based phthalonitrile polymer. Meanwhile, the phthalodinitrile resins form a homogeneous, void-free network structure, which also confirm the excellent thermal and mechanical properties of the polymers.
语种	英语
出版者	ELSEVIER SCIENCE BV
WOS记录号	WOS:000433649000001
内容类型	期刊论文
源URL	[http://ir.iccas.ac.cn/handle/121111/42887]
专题	中国科学院化学研究所
通讯作者	Liu, Wen-bin; Wang, Jun; Gao, Bao-chang
作者单位	1.Harbin Engn Univ, Inst Composite Mat, Coll Mat Sci & Chem Engn, Harbin 150001, Heilongjiang, Peoples R China 2.Qiqihar Univ, Coll Mat Sci & Engn, Qiqihar 161006, Peoples R China 3.Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Jilin, Peoples R China 4.Heilongjiang Acad Sci, Daqing Branch, Daqing 163319, Peoples R China
推荐引用方式 GB/T 7714	Wang, An-ran,Dayo, Abdul Qadeer,Zu, Li-wu,et al. Bio-based phthalonitrile compounds: Synthesis, curing behavior, thermomechanical and thermal properties[J]. REACTIVE & FUNCTIONAL POLYMERS,2018,127:1-9.
APA	Wang, An-ran.,Dayo, Abdul Qadeer.,Zu, Li-wu.,Xu, Yi-le.,Lv, Dan.,...&Gao, Bao-chang.(2018).Bio-based phthalonitrile compounds: Synthesis, curing behavior, thermomechanical and thermal properties.REACTIVE & FUNCTIONAL POLYMERS,127,1-9.
MLA	Wang, An-ran,et al."Bio-based phthalonitrile compounds: Synthesis, curing behavior, thermomechanical and thermal properties".REACTIVE & FUNCTIONAL POLYMERS 127(2018):1-9.