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Modification of side chain terminals of PEGylated molecular bottle brushes-A toolbar of molecular nanoobjects
Zou, Lei; Zhu, Wen; Chen, Yongming; Xi, Fu
刊名POLYMER
2013-01-24
卷号54期号:2页码:481-484
关键词Polymer Brush Copper Catalyzed Azide Alkyne Cycloaddition (Cuaac) Thiol-ene Radical Addition
ISSN号0032-3861
DOI10.1016/j.polymer.2012.12.020
英文摘要Water soluble molecular brush with poly(glycidyl methacrylate) (PGMA) as the main chain and monoallyl terminated poly(ethylene glycol) (PEG) as the densely grafted side chains was efficiently synthesized via grafting-onto approach by copper-catalyzed azide-alkyne cycloaddition (CuAAC) reaction. Then highly efficient post-modification of the ends of the side chains was realized through UV light induced thiol-ene radical addition. Thus polymer brushes with various side chain terminal functional groups including hydroxyl group, carboxyl group, amino group, amino acid, sulfonic group and glucose unit were obtained. (C) 2012 Elsevier Ltd. All rights reserved.
语种英语
出版者ELSEVIER SCI LTD
WOS记录号WOS:000314085000001
内容类型期刊论文
源URL[http://ir.iccas.ac.cn/handle/121111/42141]  
专题中国科学院化学研究所
通讯作者Chen, Yongming
作者单位Chinese Acad Sci, Inst Chem, Lab Polymer Phys & Chem, Beijing 100190, Peoples R China
推荐引用方式
GB/T 7714
Zou, Lei,Zhu, Wen,Chen, Yongming,et al. Modification of side chain terminals of PEGylated molecular bottle brushes-A toolbar of molecular nanoobjects[J]. POLYMER,2013,54(2):481-484.
APA Zou, Lei,Zhu, Wen,Chen, Yongming,&Xi, Fu.(2013).Modification of side chain terminals of PEGylated molecular bottle brushes-A toolbar of molecular nanoobjects.POLYMER,54(2),481-484.
MLA Zou, Lei,et al."Modification of side chain terminals of PEGylated molecular bottle brushes-A toolbar of molecular nanoobjects".POLYMER 54.2(2013):481-484.
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