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Fabrication of Macroporous/Mesoporous Carbon Nanofiber Using CaCO3 Nanoparticles as Dual Purpose Template and Its Application as Catalyst Support
Liu, Hua1,2,3; Cao, Chang-Yan1,2; Wei, Fang-Fang1,2,3; Jiang, Yan1,2,3; Sun, Yong-Bin1,2,3; Huang, Pei-Pei1,2,3; Song, Wei-Guo1,2
刊名JOURNAL OF PHYSICAL CHEMISTRY C
2013-10-17
卷号117期号:41页码:21426-21432
ISSN号1932-7447
DOI10.1021/jp4078807
英文摘要The ID hierarchical macroporous/mesoporous carbon nanofibers were prepared via electrospinning using PAN as carbon precursor and commercially available nano-CaCO3 as dual purpose template. During the carbonization process, nano-CaCO3 template decomposed and released CO2 to develop mesopores, and macropores were generated by subsequent acid removal of the as-formed CaO nanoparticles. This method is facile and low cost, allowing high-yield production of 1D hierarchical porous carbon nanofibers. The unique macro-/mesoporous structure of the nanofibers makes them a good support for anchoring palladium nanoparticles; the as-prepared catalyst shows high activity in various Suzuki cross-coupling reactions.
语种英语
出版者AMER CHEMICAL SOC
WOS记录号WOS:000326125800043
内容类型期刊论文
源URL[http://ir.iccas.ac.cn/handle/121111/42090]  
专题中国科学院化学研究所
通讯作者Song, Wei-Guo
作者单位1.Chinese Acad Sci, BNLMS, Beijing 100190, Peoples R China
2.Chinese Acad Sci, Key Lab Mol Nanostruct & Nanotechnol, Inst Chem, Beijing 100190, Peoples R China
3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
推荐引用方式
GB/T 7714
Liu, Hua,Cao, Chang-Yan,Wei, Fang-Fang,et al. Fabrication of Macroporous/Mesoporous Carbon Nanofiber Using CaCO3 Nanoparticles as Dual Purpose Template and Its Application as Catalyst Support[J]. JOURNAL OF PHYSICAL CHEMISTRY C,2013,117(41):21426-21432.
APA Liu, Hua.,Cao, Chang-Yan.,Wei, Fang-Fang.,Jiang, Yan.,Sun, Yong-Bin.,...&Song, Wei-Guo.(2013).Fabrication of Macroporous/Mesoporous Carbon Nanofiber Using CaCO3 Nanoparticles as Dual Purpose Template and Its Application as Catalyst Support.JOURNAL OF PHYSICAL CHEMISTRY C,117(41),21426-21432.
MLA Liu, Hua,et al."Fabrication of Macroporous/Mesoporous Carbon Nanofiber Using CaCO3 Nanoparticles as Dual Purpose Template and Its Application as Catalyst Support".JOURNAL OF PHYSICAL CHEMISTRY C 117.41(2013):21426-21432.
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