Sustainable catalysts for methanol carbonylation

doi:10.1039/c3gc00024a

CORC > 化学研究所 > 中国科学院化学研究所

	Sustainable catalysts for methanol carbonylation
	Li, Fengbo 1; Chen, Bingfeng 1,2; Huang, Zhijun 1; Lu, Tao 1,2; Yuan, Yin 1,2; Yuan, Guoqing 1
刊名	GREEN CHEMISTRY
	2013
卷号	15 期号:6 页码:1600-1607
ISSN号	1463-9262
DOI	10.1039/c3gc00024a
英文摘要	Methanol carbonylation is the most important process for manufacturing C2 molecules from methanol. The present industrial carbonylation has been proven to be the most successful process on economical grounds. However, there is a request to develop more sustainable and 'green' processes to overcome the inherent drawbacks. Well-designed cross-linked copolymers were prepared and used as support for the simultaneous immobilization of rhodium and iodide species. The resulting catalyst was proven to be highly active in CH3I-free methanol carbonylation and methyl acetate was the main product. Approximately 90% of methanol was converted after a two-hour reaction time at 120 degrees C under a CO pressure of 3.0 MPa. The immobilization strategy of the active species works efficiently and the present methanol carbonylation catalyst shows good recyclability. After regenerating the catalyst twice over a fifteen-batches test, the catalyst keeps an acceptable activity. The process based on the present catalyst is evidently a promising sustainable methanol carbonylation.
语种	英语
出版者	ROYAL SOC CHEMISTRY
WOS记录号	WOS:000319405900024
内容类型	期刊论文
源URL	[http://ir.iccas.ac.cn/handle/121111/41999]
专题	中国科学院化学研究所
通讯作者	Li, Fengbo
作者单位	1.Chinese Acad Sci, Beijing Natl Lab Mol Sci, Inst Chem, New Mat Lab, Beijing 100190, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
推荐引用方式 GB/T 7714	Li, Fengbo,Chen, Bingfeng,Huang, Zhijun,et al. Sustainable catalysts for methanol carbonylation[J]. GREEN CHEMISTRY,2013,15(6):1600-1607.
APA	Li, Fengbo,Chen, Bingfeng,Huang, Zhijun,Lu, Tao,Yuan, Yin,&Yuan, Guoqing.(2013).Sustainable catalysts for methanol carbonylation.GREEN CHEMISTRY,15(6),1600-1607.
MLA	Li, Fengbo,et al."Sustainable catalysts for methanol carbonylation".GREEN CHEMISTRY 15.6(2013):1600-1607.