Ultrafast Deep-Ultraviolet Laser Ionization Mass Spectrometry Applicable To Identify Phenylenediamine Isomers

doi:10.1021/acs.analchem.8b03167

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	Ultrafast Deep-Ultraviolet Laser Ionization Mass Spectrometry Applicable To Identify Phenylenediamine Isomers
	Wu, Haiming 1,3; Yuan, Chengqian 1,3; Zhang, Hanyu 1,3; Yang, Guanhua 1,3; Cui, Chaonan 1,3; Yang, Mengzhou 1,3; Bian, Wensheng 2,3; Fu, Hongbing 4; Luo, Zhixun 1,3; Yao, Jiannian 1,3
刊名	ANALYTICAL CHEMISTRY
	2018-09-04
卷号	90 期号:17 页码:10635-10640
ISSN号	0003-2700
DOI	10.1021/acs.analchem.8b03167
英文摘要	The application of low-fragmentation mass spectrometry to identify chemicals has been recognized to be of particular importance in chemistry, biomedicine, and materials science. Utilizing a customized all-solid-state pico-second-pulsed deep-ultraviolet (DUV) laser, here we present new advances into photoionization mass spectrometry. The DUV laser ionization mass spectrometry (DUV-LIMS) results in very clean spectra pertaining to minimized structure relaxation and fragmentation under the ultrafast ionization process. Typical DUV-LIMS applications are illustrated not only for small organic molecules but also for long-chain unsaturated hydrocarbons and clusters of benzene. The unique advantages of DUV-LIMS enable us to detect and analyze confusing organic compound mixtures, indicating promising applications. DUV-LIMS is also found to be applicable in the identification of phenylenediamine isomers. An in-depth analysis of reaction dynamics is provided showing how hydrogen-atom-transfer (HAT) initiates the distinguishable photodissociation of phenylenediamines under near-resonant excitation. In particular, ortho-phenylenediamine (OPD) finds a remarkable dehydrogenation product with comparable intensity to the molecular ion peak, which is associated with the quantum tunnelling tautomers, providing new subjects for studying intramolecular noncovalent interactions.
语种	英语
出版者	AMER CHEMICAL SOC
WOS记录号	WOS:000444060600074
内容类型	期刊论文
源URL	[http://ir.iccas.ac.cn/handle/121111/41898]
专题	中国科学院化学研究所
通讯作者	Luo, Zhixun
作者单位	1.Chinese Acad Sci, Inst Chem, CAS Key Lab Photochem, State Key Lab Struct Chem Unstable & Stable Speci, Beijing 100190, Peoples R China 2.Chinese Acad Sci, Inst Chem, State Key Lab Mol React Dynam, Beijing 100190, Peoples R China 3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 4.Capital Normal Univ, Dept Chem, Beijing 100048, Peoples R China
推荐引用方式 GB/T 7714	Wu, Haiming,Yuan, Chengqian,Zhang, Hanyu,et al. Ultrafast Deep-Ultraviolet Laser Ionization Mass Spectrometry Applicable To Identify Phenylenediamine Isomers[J]. ANALYTICAL CHEMISTRY,2018,90(17):10635-10640.
APA	Wu, Haiming.,Yuan, Chengqian.,Zhang, Hanyu.,Yang, Guanhua.,Cui, Chaonan.,...&Yao, Jiannian.(2018).Ultrafast Deep-Ultraviolet Laser Ionization Mass Spectrometry Applicable To Identify Phenylenediamine Isomers.ANALYTICAL CHEMISTRY,90(17),10635-10640.
MLA	Wu, Haiming,et al."Ultrafast Deep-Ultraviolet Laser Ionization Mass Spectrometry Applicable To Identify Phenylenediamine Isomers".ANALYTICAL CHEMISTRY 90.17(2018):10635-10640.