Three-liquid-phase extraction and separation of V(V) and Cr(VI) from acidic leach solutions of high-chromium vanadium-titanium magnetite

doi:10.1016/j.cjche.2018.01.023

	Three-liquid-phase extraction and separation of V(V) and Cr(VI) from acidic leach solutions of high-chromium vanadium-titanium magnetite
	Sun, Pan; Huang, Kun; Wang, Xiaoqin; Sui, Na; Lin, Jieyuan; Cao, Wenjuan; Liu, Huizhou
	2018
会议日期	JUL 12-15, 2015
会议地点	Collaborat Innovat Ctr Chem Sci & Engn, Tianjin, PEOPLES R CHINA
关键词	Three-liquid-phase extraction REDUCTION Vanadium RECOVERY Chromium FE(III) Separation SYSTEMS High-chromium vanadium-titanium magnetite TI(IV) OXIDE IONS SLAG CR
卷号	26
期号	SI
DOI	10.1016/j.cjche.2018.01.023
页码	1451 ; 1457
英文摘要	A new method by liquid-liquid-liquid three phase system, consisting of acidified primary amine N1923 (abbreviated as A-N1923), poly(ethylene glycol) (PEG) and (NH4)(2)SO4 aqueous solution, was suggested for the separation and simultaneous extraction of V(V) and Cr(VI) from the acidic leach solutions of high-chromium vanadium-titanium magnetite. Experimental results indicated that V(V) and Cr(VI) could be selectively enriched into the A-N1923 organic top phase and PEG-rich middle phase, respectively, while Al(III) and other co-existing impurity ions, such as Si(IV), Fe(III), Ti(IV), Mg(II) and Ca(II) in acidic leach solutions, could be enriched in the (NH4)(2)SO4 bottom aqueous phase. During the process for extraction and separation of V(V) and Cr(VI), almost all of impurity ions could be removed. The separation factors between V (V) and Cr(VI) could reach 630 and 908, respectively in the organic top phase and PEG middle phase, and yields of recovered V(V) and Cr(VI) in the top phase and middle phase respectively were all above 90%. Various effects including aqueous pH, A-N1923 concentration, PEG added amount and (NH4)(2)SO4 concentration on three-phase partitioning of V(V) and Cr(VI) were discussed. It was found that the partition of Cr(VI) into the PEG-rich middle phase was driven by hydrophobic interaction, while extraction of V(V) by A-N1923 resulted of anion exchange between NO3- and H2V10O284-. Stripping of V(V) and Cr(VI) from the top organic phase and the middle PEG-rich phase were achieved by mixing respectively with NaNO3 aqueous solutions and NaOH-(NH4)(2)SO4 solutions. The present work highlights a new approach for the extraction and purification of V and Cr from the complex multi-metal co-existing acidic leach solutions of high-chromium vanadium-titanium magnetite. (C) 2018 The Chemical Industry and Engineering Society of China, and Chemical Industry Press. All rights reserved.
源文献作者	Tianjin Univ, Sch Chem Engn & Technol, Natl Engn Res Ctr Distillat Technol, State Res Ctr Industrializat Crystallizat Technol
会议录	Article; Proceedings Paper
WOS记录号	WOS:000441682400003
内容类型	会议论文
源URL	[http://ir.ipe.ac.cn/handle/122111/28952]
专题	中国科学院过程工程研究所
推荐引用方式 GB/T 7714	Sun, Pan,Huang, Kun,Wang, Xiaoqin,et al. Three-liquid-phase extraction and separation of V(V) and Cr(VI) from acidic leach solutions of high-chromium vanadium-titanium magnetite[C]. 见:. Collaborat Innovat Ctr Chem Sci & Engn, Tianjin, PEOPLES R CHINA. JUL 12-15, 2015.