Design and synthesis of supramolecular functional monomers bearing urea and norbornene motifs
Wang, LL (Wang, Lulu)[ 1,2,3 ]; Lin, QF (Lin, Qifeng)[ 4 ]; Zhang, YG (Zhang, Yagang)[ 1,2,3 ]; Liu, YX (Liu, Yanxia)[ 1,2,3 ]; Yasin, A (Yasin, Akram)[ 2 ]; Zhang, LT (Zhang, Letao)[ 2 ]
刊名RSC ADVANCES
2019
卷号9期号:35页码:20058-20064
ISSN号2046-2069
DOI10.1039/c9ra01852b
英文摘要

Three sets of functional monomers namely urea-based, 2-ureido-4[1H]-primidone (UPy)-based and norbornene based functional monomers were designed and synthesized. These functional monomers (FM) were obtained in decent yields using amine and isocyanate/norbornene as starting materials. Methacrylate and styrene isocyanate with 1,4-diaminobutane/tris(2-aminoethyl)amine were chosen for the synthesis of symmetrical, asymmetrical and three-branched urea-functional monomers, respectively. UPy-based FMs were synthesized with isocyanate and 2-amino-4-hydroxy-6-methylpyrimidine. The synthesis of these monomers feature short reaction times, mild reaction conditions and no need for column chromatographic purification. Furthermore, the norbornene based FM was used for preparing molecularly imprinted polymers (MIPs) by Ring-Opening Metathesis Polymerization (ROMP). Results showed that these synthetic routes represent a convenient and useful approach for synthesis of novel functional monomers.

WOS记录号WOS:000474266800020
内容类型期刊论文
源URL[http://ir.xjipc.cas.cn/handle/365002/6029]  
专题新疆理化技术研究所_资源化学研究室
作者单位1.Xinjiang Inst Engn, Dept Chem & Environm Engn, Urumqi 830023, Peoples R China
2.Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Urumqi 830011, Peoples R China
3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
4.Chinese Acad Sci, Xinjiang Inst Ecol & Geog, Urumqi 830011, Xinjiang, Peoples R China
推荐引用方式
GB/T 7714
Wang, LL ,Lin, QF ,Zhang, YG ,et al. Design and synthesis of supramolecular functional monomers bearing urea and norbornene motifs[J]. RSC ADVANCES,2019,9(35):20058-20064.
APA Wang, LL ,Lin, QF ,Zhang, YG ,Liu, YX ,Yasin, A ,&Zhang, LT .(2019).Design and synthesis of supramolecular functional monomers bearing urea and norbornene motifs.RSC ADVANCES,9(35),20058-20064.
MLA Wang, LL ,et al."Design and synthesis of supramolecular functional monomers bearing urea and norbornene motifs".RSC ADVANCES 9.35(2019):20058-20064.
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