Design and synthesis of supramolecular functional monomers bearing urea and norbornene motifs | |
Wang, LL (Wang, Lulu)[ 1,2,3 ]; Lin, QF (Lin, Qifeng)[ 4 ]; Zhang, YG (Zhang, Yagang)[ 1,2,3 ]; Liu, YX (Liu, Yanxia)[ 1,2,3 ]; Yasin, A (Yasin, Akram)[ 2 ]; Zhang, LT (Zhang, Letao)[ 2 ] | |
刊名 | RSC ADVANCES |
2019 | |
卷号 | 9期号:35页码:20058-20064 |
ISSN号 | 2046-2069 |
DOI | 10.1039/c9ra01852b |
英文摘要 | Three sets of functional monomers namely urea-based, 2-ureido-4[1H]-primidone (UPy)-based and norbornene based functional monomers were designed and synthesized. These functional monomers (FM) were obtained in decent yields using amine and isocyanate/norbornene as starting materials. Methacrylate and styrene isocyanate with 1,4-diaminobutane/tris(2-aminoethyl)amine were chosen for the synthesis of symmetrical, asymmetrical and three-branched urea-functional monomers, respectively. UPy-based FMs were synthesized with isocyanate and 2-amino-4-hydroxy-6-methylpyrimidine. The synthesis of these monomers feature short reaction times, mild reaction conditions and no need for column chromatographic purification. Furthermore, the norbornene based FM was used for preparing molecularly imprinted polymers (MIPs) by Ring-Opening Metathesis Polymerization (ROMP). Results showed that these synthetic routes represent a convenient and useful approach for synthesis of novel functional monomers. |
WOS记录号 | WOS:000474266800020 |
内容类型 | 期刊论文 |
源URL | [http://ir.xjipc.cas.cn/handle/365002/6029] |
专题 | 新疆理化技术研究所_资源化学研究室 |
作者单位 | 1.Xinjiang Inst Engn, Dept Chem & Environm Engn, Urumqi 830023, Peoples R China 2.Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Urumqi 830011, Peoples R China 3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 4.Chinese Acad Sci, Xinjiang Inst Ecol & Geog, Urumqi 830011, Xinjiang, Peoples R China |
推荐引用方式 GB/T 7714 | Wang, LL ,Lin, QF ,Zhang, YG ,et al. Design and synthesis of supramolecular functional monomers bearing urea and norbornene motifs[J]. RSC ADVANCES,2019,9(35):20058-20064. |
APA | Wang, LL ,Lin, QF ,Zhang, YG ,Liu, YX ,Yasin, A ,&Zhang, LT .(2019).Design and synthesis of supramolecular functional monomers bearing urea and norbornene motifs.RSC ADVANCES,9(35),20058-20064. |
MLA | Wang, LL ,et al."Design and synthesis of supramolecular functional monomers bearing urea and norbornene motifs".RSC ADVANCES 9.35(2019):20058-20064. |
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