PPCP Degradation by Chlorine-UV Processes in Ammoniacal Water: New Reaction Insights, Kinetic Modeling, and DBP Formation

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	PPCP Degradation by Chlorine-UV Processes in Ammoniacal Water: New Reaction Insights, Kinetic Modeling, and DBP Formation
	Ben, Weiwei; Zhang, Ruochun; Meng, Tan; Huang, Ching-Hua; Yao, Hong; Liu, Ruini; Sun, Peizhe
刊名	ENVIRONMENTAL SCIENCE & TECHNOLOGY
	2018-07-17
卷号	52 期号:14 页码:7833-7841
ISSN号	0013-936X
文献子类	Article
英文摘要	The combination of chlorine and UV (i.e., chlorine-UV process) has been attracting more attention in recent years due to its ready incorporation into existing water treatment facilities to remove PPCPs. However, limited information is available on the impact of total ammonia nitrogen (TAN). This study investigated two model PPCPs, N,N-diethyl-3-toluamide (DEET) and caffeine (CAF), in the two stages of the chlorine-UV process (i.e., chlorination and UV/chlor(am)ine) to elucidate the impact of TAN. During chlorination, the degradation of DEET and CAF was positively correlated with the overall consumption of total chlorine by TAN. Reactive nitrogen intermediates, including HNO/NO- and ONOOH/ONOO-, along with (OH)-O-center dot were identified as major contributors to the removal of DEET and CAF. During UV irradiation, DEET and CAF were degraded under UV/chlorine or UV/NH2Cl conditions. (OH)-O-center dot and Cl-center dot were the major reactive species to degrade DEET and CAF under UV/NH2Cl conditions, whereas (OCl)-O-center dot played a major role for degrading CAF under UV/chlorine conditions. Numerical models were developed to predict the removal of DEET and CAF under chlorination-UV process. Chlorinated disinfection byproducts were detected. Overall, this study presented kinetic features and mechanistic insights on the degradation of PPCPs under the chlorine-UV process in ammoniacal water.
内容类型	期刊论文
源URL	[http://ir.rcees.ac.cn/handle/311016/41169]
专题	生态环境研究中心_环境水质学国家重点实验室
推荐引用方式 GB/T 7714	Ben, Weiwei,Zhang, Ruochun,Meng, Tan,et al. PPCP Degradation by Chlorine-UV Processes in Ammoniacal Water: New Reaction Insights, Kinetic Modeling, and DBP Formation[J]. ENVIRONMENTAL SCIENCE & TECHNOLOGY,2018,52(14):7833-7841.
APA	Ben, Weiwei.,Zhang, Ruochun.,Meng, Tan.,Huang, Ching-Hua.,Yao, Hong.,...&Sun, Peizhe.(2018).PPCP Degradation by Chlorine-UV Processes in Ammoniacal Water: New Reaction Insights, Kinetic Modeling, and DBP Formation.ENVIRONMENTAL SCIENCE & TECHNOLOGY,52(14),7833-7841.
MLA	Ben, Weiwei,et al."PPCP Degradation by Chlorine-UV Processes in Ammoniacal Water: New Reaction Insights, Kinetic Modeling, and DBP Formation".ENVIRONMENTAL SCIENCE & TECHNOLOGY 52.14(2018):7833-7841.