Sandwich Lutetacyclopentadiene with the Coordination of Lithium to the Diene Unit: Synthesis, Structure, and Transformation | |
Xu, Ling2; Wang, Yang2; Wang, Yu-Chen2; Wang, Zitao2; Zhang, Wen-Xiong1,2; Xi, Zhenfeng2 | |
刊名 | ORGANOMETALLICS |
2016-01-11 | |
卷号 | 35期号:1页码:5-8 |
ISSN号 | 0276-7333 |
DOI | 10.1021/acs.organomet.5b00957 |
文献子类 | Article |
英文摘要 | The sandwich lutetacyclopentadiene 2 can be obtained in high yield by the 1:1 reaction of the 1,4-dilithio-1,3-butadiene 1 with [Cp2LuCl]. Single-crystal X-ray diffraction of 2 reveals it as a contact ion pair with the coordination of lithium to the diene unit. This coordination mode is rare in metallacyclopentadiene chemistry. Further transformation of 2 with the inorganic salt KF and crown ethers leads to the formation of sandwich lutetacyclopentadienes 3 and 5 as separated ion pairs and of 4 as a one-dimensional coordination polymer. |
WOS关键词 | MOLECULAR-STRUCTURE ; CRYSTAL-STRUCTURE ; BUILDING-BLOCK ; METAL CENTER ; COMPLEXES ; REACTIVITY ; METALLACYCLOPENTADIENES ; LIGANDS ; METALLOCENES ; MOLYBDENUM |
WOS研究方向 | Chemistry |
语种 | 英语 |
出版者 | AMER CHEMICAL SOC |
WOS记录号 | WOS:000368048000002 |
内容类型 | 期刊论文 |
源URL | [http://cas-ir.dicp.ac.cn/handle/321008/171500] |
专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
通讯作者 | Zhang, Wen-Xiong |
作者单位 | 1.Nankai Univ, State Key Lab Elementoorgan Chem, Tianjin 300071, Peoples R China 2.Peking Univ, Coll Chem, Key Lab Bioorgan Chem & Mol Engn, Beijing Natl Lab Mol Sci,Minist Educ, Beijing 100871, Peoples R China |
推荐引用方式 GB/T 7714 | Xu, Ling,Wang, Yang,Wang, Yu-Chen,et al. Sandwich Lutetacyclopentadiene with the Coordination of Lithium to the Diene Unit: Synthesis, Structure, and Transformation[J]. ORGANOMETALLICS,2016,35(1):5-8. |
APA | Xu, Ling,Wang, Yang,Wang, Yu-Chen,Wang, Zitao,Zhang, Wen-Xiong,&Xi, Zhenfeng.(2016).Sandwich Lutetacyclopentadiene with the Coordination of Lithium to the Diene Unit: Synthesis, Structure, and Transformation.ORGANOMETALLICS,35(1),5-8. |
MLA | Xu, Ling,et al."Sandwich Lutetacyclopentadiene with the Coordination of Lithium to the Diene Unit: Synthesis, Structure, and Transformation".ORGANOMETALLICS 35.1(2016):5-8. |
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