A "copolymer-co-morphology" conception for shape-controlled synthesis of Prussian blue analogues and as-derived spinel oxides

doi:10.1039/c5nr07193c

	A "copolymer-co-morphology" conception for shape-controlled synthesis of Prussian blue analogues and as-derived spinel oxides
	Li, Xuning 3,4; Yuan, Lizhi 4,5; Wang, Junhu 3; Jiang, Luhua 5; Rykov, Alexandre I.3; Nagy, Denes L.1; Bogdan, Csilla 1; Ahmed, Mamdouh A.6; Zhu, Kaiyue 2,4; Sun, Gongquan 5
刊名	NANOSCALE
	2016
卷号	8 期号:4 页码:2333-2342
ISSN号	2040-3364
DOI	10.1039/c5nr07193c
文献子类	Article
英文摘要	The morphologically and compositionally controlled synthesis of coordination polymers and spinel oxides is highly desirable for realizing new advanced nanomaterial functionalities. Here we develop a novel and scalable strategy, containing a "copolymer-co-morphology" conception, to shape-controlled synthesis of various types of Prussian blue analogues (PBAs). Three series of PBAs MyFe1-y[Co(CN)(6)](0.67)center dot nH(2)O (MyFe1-y-Co, M = Co, Mn and Zn) with well-controlled morphology have been successfully prepared through this strategy. Using MnyFe1-y-Co PBAs as the model, by increasing the relative content of Mn, flexible modulation of the morphology could be easily realized. In addition, a series of porous MnxFe1.8-xCo1.2O4 nano-dices with well-inherited morphologies and defined cation distribution could be obtained through a simple thermal treatment of the PBAs. All these results demonstrate the good universality of this novel strategy. When evaluated as an electrocatalyst, the octahedral-site Mn-III/Mn-IV content in MnxFe1.8-xCo1.2O4, mainly determined by sensitive Fe-57 Mossbauer in combination with X-ray photoelectron spectroscopic techniques, was discovered to be directly correlated with the oxygen reduction/evolution reaction (ORR/OER) activity.
WOS关键词	METAL-ORGANIC-FRAMEWORKS ; LITHIUM-ION BATTERIES ; OXYGEN REDUCTION REACTION ; HIGH-PERFORMANCE ANODES ; COBALT FERRITE NANOPARTICLES ; MAGNETIC-PROPERTIES ; HOLLOW STRUCTURES ; MANGANESE OXIDES ; ALKALINE MEDIA ; NANOSCALE
WOS研究方向	Chemistry ; Science & Technology - Other Topics ; Materials Science ; Physics
语种	英语
出版者	ROYAL SOC CHEMISTRY
WOS记录号	WOS:000368860900068
内容类型	期刊论文
源URL	[http://cas-ir.dicp.ac.cn/handle/321008/171318]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
通讯作者	Li, Xuning; Wang, Junhu; Jiang, Luhua
作者单位	1.Hungarian Acad Sci, Wigner Res Ctr Phys, Inst Particle & Nucl Phys, POB 49, H-1525 Budapest, Hungary 2.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China 3.Chinese Acad Sci, Dalian Inst Chem Phys, Mossbauer Effect Data Ctr, Dalian 116023, Peoples R China 4.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 5.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, Dalian 116023, Peoples R China 6.Al Azhar Univ, Fac Sci, Dept Phys, Cairo, Egypt
推荐引用方式 GB/T 7714	Li, Xuning,Yuan, Lizhi,Wang, Junhu,et al. A "copolymer-co-morphology" conception for shape-controlled synthesis of Prussian blue analogues and as-derived spinel oxides[J]. NANOSCALE,2016,8(4):2333-2342.
APA	Li, Xuning.,Yuan, Lizhi.,Wang, Junhu.,Jiang, Luhua.,Rykov, Alexandre I..,...&Yang, Weishen.(2016).A "copolymer-co-morphology" conception for shape-controlled synthesis of Prussian blue analogues and as-derived spinel oxides.NANOSCALE,8(4),2333-2342.
MLA	Li, Xuning,et al."A "copolymer-co-morphology" conception for shape-controlled synthesis of Prussian blue analogues and as-derived spinel oxides".NANOSCALE 8.4(2016):2333-2342.