Iron/ABNO-Catalyzed Aerobic Oxidation of Alcohols and Ketones under Ambient Atmosphere

doi:10.1021/acs.joc.6b00009

	Iron/ABNO-Catalyzed Aerobic Oxidation of Alcohols and Ketones under Ambient Atmosphere
	Wang, Lianyue 1; Shang, SenSen 1,2; Li, Guosong 1; Ren, Lanhui 1,2; Lv, Ying 1; Gao, Shuang 1
刊名	JOURNAL OF ORGANIC CHEMISTRY
	2016-03-04
卷号	81 期号:5 页码:2189-2193
ISSN号	0022-3263
DOI	10.1021/acs.joc.6b00009
文献子类	Article
英文摘要	We report a new Fe(NO3)(3)center dot 9H(2)O/9-azabicyclo-[3.3.1]nonan-N-oxyl catalyst system that enables efficient aerobic oxidation of a broad range of primary and secondary alcohols to the corresponding aldehydes and ketones at room temperature with ambient air as the oxidant. The catalyst system exhibits excellent activity and selectivity for primary aliphatic alcohol oxidation. This procedure can also be scaled up. Kinetic analysis demonstrates that C-H bond cleavage is the rate-determining step and that cationic species are involved in the reaction.
WOS关键词	SECONDARY BENZYLIC ALCOHOLS ; MOLECULAR-OXYGEN ; ROOM-TEMPERATURE ; MILD CONDITIONS ; PROPARGYLIC ALCOHOLS ; CARBONYL-COMPOUNDS ; ORGANIC-SYNTHESIS ; ALDEHYDES ; EFFICIENT ; IRON
WOS研究方向	Chemistry
语种	英语
出版者	AMER CHEMICAL SOC
WOS记录号	WOS:000371753900051
内容类型	期刊论文
源URL	[http://cas-ir.dicp.ac.cn/handle/321008/171056]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
通讯作者	Gao, Shuang
作者单位	1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, Dalian 116023, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China
推荐引用方式 GB/T 7714	Wang, Lianyue,Shang, SenSen,Li, Guosong,et al. Iron/ABNO-Catalyzed Aerobic Oxidation of Alcohols and Ketones under Ambient Atmosphere[J]. JOURNAL OF ORGANIC CHEMISTRY,2016,81(5):2189-2193.
APA	Wang, Lianyue,Shang, SenSen,Li, Guosong,Ren, Lanhui,Lv, Ying,&Gao, Shuang.(2016).Iron/ABNO-Catalyzed Aerobic Oxidation of Alcohols and Ketones under Ambient Atmosphere.JOURNAL OF ORGANIC CHEMISTRY,81(5),2189-2193.
MLA	Wang, Lianyue,et al."Iron/ABNO-Catalyzed Aerobic Oxidation of Alcohols and Ketones under Ambient Atmosphere".JOURNAL OF ORGANIC CHEMISTRY 81.5(2016):2189-2193.